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Processes for the preparation of a macromer and a polymer, macromer, polymer polyol, flexible polyurethane foam, and, molded article

机译:大分子单体和聚合物的制备方法,大分子单体,聚合物多元醇,软质聚氨酯泡沫和模制品

摘要

"PROCESSES FOR PREPARING A MACROMER AND POLYMER POLYMER, MACROMER, POLYMER POLYMER, FLEXIBLE POLYURETHANE FOAM, AND, MOLDED ARTICLE". Process for the preparation of a suitable macromer as a stabilizer precursor in a polymer polyol, the process of which comprises the reaction of a polyol with a cyclic dicarboxylic acid anhydride that does not contain any polymerizable double bond and the subsequent reaction of the adduct thus obtained with a epoxy compound containing a polymerizable double bond. The resulting macromer has a nominal molecular weight of at least 4000 and can be applied to the preparation of a polymer polyol by polymerization in a polyol based on at least one ethylenically unsaturated monomer in the presence of a polymerization initiator and a macromer. The polymer polyol thus obtained is very suitable for the manufacture of flexible polyurethane foams.
机译:“制备宏观聚合物和聚合物的方法,宏观聚合物,聚合物聚合物,柔性聚氨酯泡沫和模塑制品”。制备合适的大分子单体作为聚合物多元醇中的稳定剂前体的方法,该方法包括多元醇与不包含任何可聚合双键的环状二羧酸酐的反应以及由此获得的加合物的随后反应与含有可聚合双键的环氧化合物。所得的大分子单体的标称分子量为至少4000,并且可以在聚合引发剂和大分子单体的存在下,通过在基于至少一种烯键式不饱和单体的多元醇中的聚合反应而用于制备聚合物多元醇。如此获得的聚合物多元醇非常适合于制造软质聚氨酯泡沫。

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