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PROCESS FOR REDUCING THE RADIOACTIVITY OF PHOSPHORUS CONTAINING CHEMICAL FERTILIZERS

机译:降低含磷化学肥料的放射性的方法

摘要

The invention relates to a process for reducing natural radioactivity during the processes for preparing phosphorus containing fertilizers, also recovering uranium and rare earths. According to the invention, the process consists in settling the radium with barium sulphate, retaining the radium as residue, by filtering, followed by extracting the uranium, rare earths, vanadium, iron, chromium etc with di(2-ethylhexyl)phosphate ester and tri-n-octylphosphinic or tributylphosphinic oxide - using as diluent an aliphatic hydrocarbon, separating the extract from phosphonitric solutions or phosphoric acid having a low reactivity and passing it through a plurality of stirring, separating and stripping stages for producing by successive filtrations first a rare earth concentrate and then a uranium concentrate, and recirculating the depleted extract of uranium and rare earth, thereafter.
机译:本发明涉及一种在制备含磷肥料的过程中降低自然放射性的方法,该方法还回收铀和稀土。根据本发明,该方法包括用硫酸钡沉淀镭,保留镭作为残留物,通过过滤,然后用磷酸二(2-乙基己基)酯萃取铀,稀土,钒,铁,铬等。三正辛基次膦酸酯或三丁基次膦酸酯氧化物-使用脂族烃作为稀释剂,从具有低反应性的膦酸溶液或磷酸中分离提取物,并将其经过多个搅拌,分离和汽提阶段,以首先通过连续过滤进行生产浓缩物,然后再浓缩铀,然后再循环贫化的铀和稀土提取物。

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