首页> 外国专利> METHOD OF PRODUCING AN ELASTOMER BLEND THAT IS SIMILAR TO THERMOPLASTIC ELASTOMERS, ON THE BASIS OF RECLAIMED RUBBER OR WASTE RUBBER

METHOD OF PRODUCING AN ELASTOMER BLEND THAT IS SIMILAR TO THERMOPLASTIC ELASTOMERS, ON THE BASIS OF RECLAIMED RUBBER OR WASTE RUBBER

机译:以再生橡胶或废橡胶为基础生产类似于热塑性塑料弹性体的弹性体混合物的方法

摘要

The invention relates to a method of producing an elastomer blend that is similar to thermoplastic elastomers on the basis of reclaimed rubber or waste rubber. According to this method, reclaimed rubber or waste rubber that has been reduced to powdered rubber is processed to compounds by subjecting it to a melt-mixing process in a mixer together with a thermoplastic material and at least one stabilizer in different weight percentages. The aim of the invention is to improve this method so that a mixture that consists of two phases that are usually incompatible, namely the powdered rubber and a thermoplastic material, is processed to a blend that is characterized by the properties of thermoplastic elastomers. Said blend should have a constant quality, should be reproducible and repeatedly recyclable and the method should allow the conversion in a melt-mixing process over a relatively short mixing period by choosing suitable materials for the thermoplastic constituent and other additives. To this end, at least one polypropylene copolymer or a mixture thereof with at least one polypropylene type is melted in the mixer and powdered rubber, at least part of which has been pre-swelled in a radical donor, is dosed to the melt. The powdered rubber is dispersed in the plastic matrix by applying high shearing strains and admixing radical-forming agents in order to couple the two phases that consist of the powdered rubber and the polypropylene copolymer or a mixture thereof in accordance with defined mixing parameters. The dynamic stabilization process is carried out at a temperature of the mixture that is above the melt temperature of the polypropylene copolymer or the mixture thereof but below the decomposition temperature of the powdered rubber and over a mixing period that allows the reaction of the radical former.
机译:本发明涉及一种基于再生橡胶或废橡胶生产类似于热塑性弹性体的弹性体混合物的方法。根据该方法,将再生的橡胶或已被还原成粉状橡胶的废橡胶通过在混合器中与热塑性材料和至少一种不同重量百分比的稳定剂一起进行熔融混合处理而被加工成复合物。发明内容本发明的目的是改进该方法,使得由通常不相容的两相组成的混合物,即橡胶粉和热塑性材料,被加工成以热塑性弹性体的特性为特征的共混物。所述共混物应具有恒定的质量,应可重复生产和可重复利用,并且该方法应通过选择适合热塑性组分和其他添加剂的材料,在相对短的混合时间内以熔融混合方法进行转化。为此,将至少一种聚丙烯共聚物或其与至少一种聚丙烯类型的混合物在混合器中熔融,并将至少一部分已在自由基供体中预溶胀的橡胶粉加入到熔体中。通过施加高剪切应变并混合自由基形成剂,将粉末状橡胶分散在塑料基质中,以便根据定义的混合参数将由粉末状橡胶和聚丙烯共聚物或其混合物组成的两相耦合。动态稳定化过程是在混合物的温度高于聚丙烯共聚物或其混合物的熔融温度但低于粉状橡胶的分解温度的温度下进行的,并且在允许自由基形成剂反应的混合时间内进行。

著录项

  • 公开/公告号EP1144493B1

    专利类型

  • 公开/公告日2002-10-23

    原文格式PDF

  • 申请/专利权人 MICHAEL HANNES;SCHOLZ HENRIK;

    申请/专利号EP20000945529

  • 发明设计人 SCHOLZ HENRIK;MICHAEL HANNES;

    申请日2000-05-17

  • 分类号C08J11/00;

  • 国家 EP

  • 入库时间 2022-08-22 00:34:23

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