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METHOD FOR DIRECT MEASUREMENT OF POLYCARBONATE COMPOSITION BY FLUORESCENCE

机译:荧光法直接测定聚碳酸酯的组成

摘要

The present invention provides a method for directly determining the concentration of a target species, such as Fries product, in a composition comprising aromatic carbonate chain units. In an exemplary embodiment, the method includes the steps of irradiating a portion of the composition with electromagnetic radiation at an excitation wavelength sufficient to cause the target species to emit a fluorescence spectrum; detecting at least a portion of the fluorescence spectrum; and determining the concentration of the target species from the fluorescence spectrum. In addition to detecting Fries product in formed polycarbonate materials, the method can also be utilized to directly determine the concentration of a target species in parallel polycarbonate reactor systems.
机译:本发明提供了一种直接确定包含芳香族碳酸酯链单元的组合物中的目标物质例如弗里斯产品的浓度的方法。在一个示例性的实施方案中,该方法包括以下步骤:以足以引起靶物质发射荧光光谱的激发波长用电磁辐射照射组合物的一部分;以及将所述组合物的一部分发射出去。检测至少一部分荧光光谱;从荧光光谱确定目标物质的浓度。除了检测形成的聚碳酸酯材料中的弗里斯产品外,该方法还可用于直接确定平行聚碳酸酯反应器系统中目标物质的浓度。

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