首页> 外国专利> Preparation of enol ethers, useful in e.g. pharmaceutical, agrochemical or cosmetics synthesis or as monomer for polymer, uses alkali alcoholate in polar aprotic solvent in reaction of alcohol with alkyne and/or alkadiene

Preparation of enol ethers, useful in e.g. pharmaceutical, agrochemical or cosmetics synthesis or as monomer for polymer, uses alkali alcoholate in polar aprotic solvent in reaction of alcohol with alkyne and/or alkadiene

机译:烯醇醚的制备,例如可用于医药,农业化学或化妆品合成或作为聚合物的单体,在醇与炔烃和/或链二烯的反应中,在极性非质子传递溶剂中使用碱式醇盐

摘要

Preparation of enol ethers (I) by reacting alcohols (II) with alkynes (IIIA) and/or alkadienes (IIIB) and is carried out in the presence of an alkali alcoholate and a polar aprotic solvent. Preparation of enol ethers of formula (I) by reacting alcohols of formula (II) with alkynes of formula (IIIA) and/or alkadienes of formula (IIIB) of the given formulae is carried out in the presence of an alkali alcoholate and a polar aprotic solvent. R1-R3 = H or an organic group containing carbon; and R4 = optionally substituted alkyl.
机译:通过使醇(II)与炔烃(IIIA)和/或链二烯(IIIB)反应来制备烯醇醚(I),并在碱金属醇化物和极性非质子溶剂的存在下进行。通过使式(II)的醇与式(IIIA)的炔烃和/或给定式的式(IIIB)的链二烯反应,制备式(I)的烯醇醚是在碱式醇盐和极性化合物存在下进行的。非质子溶剂。 R1-R3 = H或含碳的有机基团; R 4 =任选取代的烷基。

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