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Removing organic sulfur compounds from higher hydrocarbons and gases, such as natural gas, containing water vapor involves adjusting content of gaseous organic sulfur

机译:从含水蒸气的高级烃和气体(例如天然气)中去除有机硫化合物涉及调整气态有机硫的含量

摘要

The content of gaseous organic sulfur compounds in the pure gas is adjusted to a residual concentration value of 5-20 mg/Nm3 by controlling the residence time in the adsorber bed by changing the charge height by a factor of 1.5-4. The remaining amount of sulfur compounds with the condensate produced in the regeneration step before or during condensation. Process for removing organic sulfur compounds from higher hydrocarbons and gases, such as natural gas, containing water vapor using solid adsorbents such as activated charcoal, molecular sieve, carbon molecular sieve, silica gel and KC pearls comprises feeding the crude gas mixture through a first adsorber bed filled with adsorbent to simultaneously adsorb the hydrocarbons and water vapor; driving off the hydrocarbons and water vapor using a partial stream of crude gas heated to regeneration temperature from a second previously charged adsorber bed; condensing from the desorption gas by cooling; and removing in a separator. The remaining regeneration gas is recycled to the crude gas stream. The content of gaseous organic sulfur compounds in the pure gas is adjusted to a residual concentration value of 5-20 mg/Nm3 by controlling the residence time in the adsorber bed by changing the charge height by a factor of 1.5-4. The remaining amount of sulfur compounds with the condensate produced in the regeneration step before or during condensation.
机译:通过将装料高度改变1.5-4倍来控制在吸附床中的停留时间,从而将纯净气体中气态有机硫化合物的含量调整为残留浓度值5-20 mg / Nm 3。冷凝之前或期间在再生步骤中产生的冷凝物中残留的硫化合物。使用诸如活性炭,分子筛,碳分子筛,硅胶和KC珍珠之类的固体吸附剂从含有水蒸气的高级烃和气体(例如天然气)中除去有机硫化合物的方法包括通过第一吸附器进料原油混合物装有吸附剂的床,可同时吸附碳氢化合物和水蒸气;使用从第二个预先装满的吸附床中加热到再生温度的部分粗煤气驱除碳氢化合物和水蒸气;通过冷却从解吸气体中冷凝;并在分离器中取出。剩余的再生气体循环到粗气流中。通过将装料高度改变1.5-4倍来控制在吸附床中的停留时间,从而将纯净气体中气态有机硫化合物的含量调整为残留浓度值5-20 mg / Nm 3。冷凝之前或期间在再生步骤中产生的冷凝物中残留的硫化合物。

著录项

  • 公开/公告号DE10034941A1

    专利类型

  • 公开/公告日2002-01-24

    原文格式PDF

  • 申请/专利权人 SILICA VERFAHRENSTECHNIK GMBH;

    申请/专利号DE2000134941

  • 发明设计人 HOEHNE GERT;SCHLICHT BURKHARD;

    申请日2000-07-12

  • 分类号C10L3/00;C10L3/10;B01D53/02;

  • 国家 DE

  • 入库时间 2022-08-22 00:27:34

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