One step process for making alpha-Hydroxy by oxidation of compounds c = c unsaturated hydroperoxides.

摘要

The invention relates to a method in a single step to produce {the} -hidroxiéteres corresponding to formulas (I) and (II), by oxidation of olefinic substrates with organic hydroperoxides and opening of the oxirane ring resulting by alcohols monohydric or polyhydric. As catalyst system can be used molybdenum compounds in combination with boron trifluoride, aluminum oxide, 1,8-diazabicyclo- [5.4.0] undec-7-ene or 1,4-diazabicyclo [2.2.2] octane .