An inorganic-metal composite body exhibiting PTC behavior at a trip point temperature ranging from 40°C - 300°C, including an electrically insulating inorganic matrix having a room temperature resistivity of at least 1 x 106 Ω·cm, and electrically conductive particles uniformly dispersed in the matrix and forming a three-dimensional conductive network extending from a first surface of said body to an opposed second surface thereof wherein the composite body has a room temperature resistivity of no more than 10 Ω·cm and a high temperature resistivity of at least 100 Ω·cm. Preferably, the electrically conductive particles are made of a Bi-based alloy containing at least 50 wt % Bi, and have an average diameter, ϕave, of 5-50µm and a 3σ particle size distribution of 0.5 ϕave-2.0 ϕave. Also disclosed is an inorganic PTC device including an intermediate electrode layer to insure adhesion of outer termination electrodes to the PTC composite body, and a method of forming the composite body, which method effectively deals with the volatility of the electrically conductive particles.
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机译:在40°C-300°C的跳变点温度下表现出PTC行为的无机金属复合体,包括电绝缘的无机基质,其室温电阻率至少为1 x 10 6 Sup>Ω ·cm,并且导电颗粒均匀地分散在基质中并形成从所述主体的第一表面延伸到其相对的第二表面的三维导电网络,其中复合主体的室温电阻率不超过10Ω·厘米,高温电阻率至少为100Ω·cm。优选地,导电颗粒由包含至少50wt%的Bi的Bi基合金制成,并且具有5-50μm的平均直径ϕ ave Sub>和3σ的粒度分布为0.5 Sub ave Sub> -2.0 ϕ ave Sub>。还公开了一种无机PTC装置,其包括确保外部终端电极对PTC复合体的粘附的中间电极层,以及形成复合体的方法,该方法有效地处理了导电颗粒的挥发性。
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