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Nickel reforming catalyst and preparing method of synthesis gas or hydrogen from natural gas by steam reforming

机译:镍重整催化剂及由蒸汽重整制取天然气合成气或氢气的方法

摘要

PURPOSE: According to steam reforming reaction using nickel reforming catalyst(Ni/Ce-ZrO2) where synthesis gas containing hydrogen as primary ingredient is prepared from natural gas comprising primary methane, the present nickel reforming catalyst(Ni/Ce-ZrO2) has superior methane conversion rate when used as catalyst for steam reforming. CONSTITUTION: The nickel reforming catalyst(Ni/Ce-ZrO2) for preparing synthesis gas is characterized in that zirconia coated with cerium 0.01-1.0mol.% is further supported with nickel 5-20wt.%. The method for preparing synthesis gas from natural gas by steam reforming is performed by steam reforming reaction under operation conditions that reaction a mole ratio of methane and steam is 1:2-7, a reaction temperature is 600 to 1000deg.C, a reaction pressure is 0.5-30atm and a space velocity is 1000-500000cc.
机译:用途:根据使用镍重整催化剂(Ni / Ce-ZrO2)的蒸汽重整反应,其中以氢为主要成分的天然气制得的氢为主要成分的合成气,本镍重整催化剂(Ni / Ce-ZrO2)具有较高的甲烷用作蒸汽重整的催化剂时的转化率。组成:用于制备合成气的镍重整催化剂(Ni / Ce-ZrO2),其特征在于,包覆有0.01-1.0mol。%的铈的氧化锆还负载有5-20wt。%的镍。通过水蒸气重整从天然气中制备合成气的方法是通过水蒸气重整反应在甲烷与水蒸气的摩尔比为1:2-7,反应温度为600至1000℃,反应压力的操作条件下进行的。是0.5-30atm,空速是1000-500000cc。

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