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PHOSPHORUS YLIDES, METHOD FOR THEIR PREPARING AND INTERMEDIATE COMPOUNDS

机译:磷盐,其制备方法和中间体

摘要

FIELD: organophosphorus compounds. SUBSTANCE: invention relates to novel phosphorus ylides of the formula (I): where R1, R2, R3 represent amino-group R'R''N where R' and R'' represent C1-C6-alkyl; R4 represents H, Me; R5 represents polymeric carrier of polystyrene type of the formula (S): where n, n' and m are whole numbers = 1 or more. Compounds of the formula (I) can be used as slightly nucleophilic strong bases. Invention describes also intermediate compounds of the formula: where R1-R5 mean above indicated values; Y⊖ means anion. EFFECT: improved preparing method, valuable chemical properties of compounds. 4 cl, 1 tbl, 9 ex
机译:领域:有机磷化合物。物质:本发明涉及式(I)的新型磷酰基:<图像文件=“ 00000004.GIF” he =“ 18” id =“ imag00000004” imgContent =“ undefined” imgFormat =“ GIF” wi =“ 37” / >其中R 1 ,R 2 ,R 3 表示氨基R'R''N,其中R'和R''表示C 1 -C 6 -烷基; R 4 代表H,Me; R 5 表示式(S)的聚苯乙烯类型的聚合物载体:,其中n,n'和m是整数= 1或更大。式(I)的化合物可用作稍微亲核的强碱。本发明还描述了下式的中间化合物:<图像文件=“ 00000006.GIF” he =“ 18” id =“ imag00000006” imgContent =“未定义” imgFormat =“ GIF” wi =“ 35” />其中R 1 -R 5 均高于指示值; Y &ominus; 表示阴离子。效果:改进的制备方法,有价值的化合物化学性质。 4 cl,1 tbl,9前

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