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Catalyst for synthesis of 2 carbon oxygenates comprises rhodium, manganese and alkali metal supported on zeolite or mesoporous molecular sieve

机译:合成2种碳氧化物的催化剂包括负载在沸石或介孔分子筛上的铑,锰和碱金属

摘要

A supported rhodium containing catalyst (I) comprises 0.01-10 wt.% rhodium, 0-10 wt.% manganese and 0-10 wt.% of an alkali metal comprising lithium, sodium and/or potassium and is supported on a zeolite or mesoporous molecular sieve having an average pore diameter of 0.5-30 nm and a specific surface area of 100-1500 m2/g. Independent claims are included for: (1) a process for the production of the catalyst (I) by impregnation of the inert support with an aqueous or organic solution of the catalyst metal compounds, drying, calcining and reducing; and (2) a process for the production of 2C-oxygenates by reaction of CO and H2 in the presence of the catalyst (I).
机译:负载型含铑催化剂(I)包含0.01-10重量%的铑,0-10重量%的锰和0-10重量%的包含锂,钠和/或钾的碱金属,并负载在沸石或沸石上。具有0.5-30nm的平均孔径和100-1500m 2 / g的比表面积的中孔分子筛。包括以下独立权利要求:(1)通过用催化剂金属化合物的水溶液或有机溶液浸渍惰性载体,干燥,煅烧和还原来制备催化剂(I)的方法; (2)在催化剂(I)的存在下通过CO和H 2的反应生产2C-含氧化合物的方法。

著录项

  • 公开/公告号DE10132500A1

    专利类型

  • 公开/公告日2003-01-23

    原文格式PDF

  • 申请/专利权人 BASF AG;

    申请/专利号DE2001132500

  • 申请日2001-07-05

  • 分类号B01J29/04;B01J29/74;C07C1/10;B01J29/78;

  • 国家 DE

  • 入库时间 2022-08-21 23:42:51

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