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Preparation of oligomeric silsesquioxane compounds, useful for the modification of polymers, by direct base catalysis of the corresponding silicon compound using a specific initial ratio of compound to base
Preparation of oligomeric silsesquioxane compounds, useful for the modification of polymers, by direct base catalysis of the corresponding silicon compound using a specific initial ratio of compound to base
Oligomeric silsesquioxane compounds are prepared directly by base catalysis of the corresponding silicon compound, using an initial ratio of compound to base of 500:1-3:1. Oligomeric silsesquioxane compounds of formula R1aR2bR3cR4dR5eR6fR7gR8hO12 and structure (I) are prepared directly by base catalysis of RSiX3 , where the ratio of RSiX3 to base at the beginning of the reaction is 500:1-3:1. R, R1-R8 = optionally substituted (cyclo)alkyl, (cyclo)alkenyl, (cyclo)alkynyl, (hetero)aryl or H; X = a hydrolyzable or condensable group; and a+b+c+d+e+f+g+h = 8.
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机译:寡聚倍半硅氧烷化合物是通过相应的硅化合物的碱催化直接制备的,化合物与碱的初始比例为500:1-3:1。式R 1 aR 2 bR 3 cR 4 dR 5 eR 6 eR 6 gR 8 gR 8 hO12的低聚倍半硅氧烷化合物和结构(I)是通过碱催化RSiX3,其中反应开始时RSiX3与碱的比例为500:1-3:1。 R,R 1 -R 8 =任选取代的(环)烷基,(环)烯基,(环)炔基,(杂)芳基或H; X =可水解或可缩合的基团;并且a + b + c + d + e + f + g + h = 8。
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