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Spiropyrans, optically active spiropyrans, as well as their use
Spiropyrans, optically active spiropyrans, as well as their use
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机译:螺吡喃,旋光螺吡喃及其用途
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摘要
A spiropyran compound represented by general formula (1), an optically active spiropyran compound prepared by introducing asymmetry into the spirocarbon atom of the above compound, and an optically functional material prepared therefrom. In said formula (1) R1 represents C¿1?-C20 alkyl, aralkyl, hydroxyethyl, methacryloxymethyl or methacryloxyethyl; R?2, R3, R4 and R5¿ represent each independently hydrogen, C¿1?-C6 alkyl, aryl, aralkyl, C1-C5 alkoxy, hydroxymethyl, carboxyl, halogen, amino, cyano, trichloromethyl, trifluoromethyl or nitro; R?6 and R7¿ represent each independently hydrogen, C¿1?-C6 alkyl, aryl, aralkyl, halogen, cyano or nitro; R?8¿ represents C¿1?-C6 alkyl, hydroxymethyl, carboxyl, methoxycarbonyl, methacryloxymethyl or vinyl; at least one of R?1¿ through R8 is substituted by a group functioning as an agent for optical resolution; and X represents oxygen or sulfur.
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机译:由通式(1)表示的螺吡喃化合物,通过将不对称性引入上述化合物的螺碳原子中而制备的旋光性螺吡喃化合物以及由此制备的光学功能材料。上述式(1)中,R 1表示碳原子数1〜20的烷基,芳烷基,羟乙基,甲基丙烯酰氧基甲基或甲基丙烯酰氧基乙基。 R 2,R 3,R 4和R 5分别独立地表示氢,C 1 -C 6烷基,芳基,芳烷基,C 1 -C 5烷氧基,羟甲基,羧基,卤素,氨基,氰基,三氯甲基,三氟甲基或硝基。 R 6和R 7分别独立地代表氢,C 1 -C 6烷基,芳基,芳烷基,卤素,氰基或硝基。 R 8是C 1 -C 6烷基,羟甲基,羧基,甲氧基羰基,甲基丙烯酰氧基甲基或乙烯基。 R 1〜R 8中的至少一个被作为光学拆分剂的基团所取代。 X表示氧或硫。
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