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Spiropyran compounds and optically active spiropyran compounds and their use

机译:螺吡喃化合物和旋光螺吡喃化合物及其用途

摘要

The present invention relates to a spiropyran compound represented by the formula (1); an optically active spiropyran compound wherein an asymmetric center is introduced on a spirocarbon; and optical functional materials using these compounds, ##STR1## wherein R.sup.1 is alkyl group having 1 to 20 carbon atoms, aralkyl group, hydroxyethyl group, methacryloxymethyl group or methacryloxyethyl group; R.sup.2, R. sup.3, R. sup.4 and R.sup.5 are the same or different and are each hydrogen atom, alkyl group having 1 to 6 carbon atoms, aryl group, aralkyl group, alkoxy group having 1 to 5 carbon atoms, hydroxymethyl group, carboxyl group, halogen atom, amino group, cyano group, trichloromethyl group, trifluoromethyl group or nitro group; R.sup.6 and R.sup.7 are the same or different and are each hydrogen atom, alkyl group having 1 to 6 carbon atoms, aryl group, aralkyl group, halogen atom, cyano group or nitro group; R.sup.6 is alkyl group having 1 to 6 carbon atoms, hydroxymethyl group, carboxyl group, methoxycarbonyl group, methacryloxymethyl group or vinyl group; at least one of R.sup.1 to R.sup. 8 is substituted with a substituent having properties as a reagent for optical resolution; and X is oxygen atom or sulfur atom.
机译:本发明涉及式(1)表示的螺吡喃化合物。在螺碳上引入不对称中心的旋光螺吡喃化合物;以及使用这些化合物的光学功能材料,其中R 1是具有1至20个碳原子的烷基,芳烷基,羟乙基,甲基丙烯酰氧基甲基或甲基丙烯酰氧基乙基。 R.sup.2,R.sup.3,R.sup.4和R.sup.5相同或不同,分别为氢原子,具有1-6个碳原子的烷基,芳基,芳烷基,烷氧基具有1至5个碳原子的基团,羟甲基,羧基,卤原子,氨基,氰基,三氯甲基,三氟甲基或硝基; R 6和R 7相同或不同,分别为氢原子,具有1-6个碳原子的烷基,芳基,芳烷基,卤素原子,氰基或硝基。 R 6是具有1-6个碳原子的烷基,羟甲基,羧基,甲氧基羰基,甲基丙烯酰氧基甲基或乙烯基; R.sup.1到R.sup。中的至少一个。 8被具有作为光学拆分试剂的性质的取代基取代; X为氧原子或硫原子。

著录项

  • 公开/公告号US5521269A

    专利类型

  • 公开/公告日1996-05-28

    原文格式PDF

  • 申请/专利权人 OTSUKA KAGAKU KABUSHIKI KAISHA;

    申请/专利号US19940335756

  • 发明设计人 AKIRA MIYASHITA;

    申请日1994-11-14

  • 分类号C08F126/06;C08F124/00;C08F128/00;C07D487/10;C07D491/107;C07D495/10;

  • 国家 US

  • 入库时间 2022-08-22 03:38:31

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