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Ruthenium catalysts on a s102-based carrier material for catalytic hydrogenation of saccharides

机译:s102基载体材料上的钌催化剂,用于糖的催化加氢

摘要

Novel ruthenium catalysts can be obtained by: ;i) treating a support material based on amorphous silicon dioxide one or more times with a halogen-free aqueous solution of a low molecular weight ruthenium compound and subsequently drying the treated support material at below 200° C., ;ii) reducing the solid obtained in i) by means of hydrogen at from 100 to 350° C., ;where step ii) is carried out directly after step i). These catalysts can be used for the catalytic hydrogenation of monosaccharides and disaccharides to produce sugar alcohols, with the exception of sorbitol.
机译:新型钌催化剂可通过以下方法获得:i)用低分子量钌化合物的无卤素水溶液将基于无定形二氧化硅的载体材料处理一次或多次,然后在200°C以下干燥处理过的载体材料。 ;; ii)通过氢气在100-350℃下还原i)中获得的固体。 C.,其中步骤ii)在步骤i)之后直接执行。这些催化剂可用于单糖和二糖的催化加氢以生产糖醇(山梨醇除外)。

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