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Nucleophilic kinetic resolution of cyclic substrates using silyl azides
Nucleophilic kinetic resolution of cyclic substrates using silyl azides
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机译:硅烷基叠氮化物对环状底物的亲核动力学拆分
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摘要
The present invention relates to a process for stereoselective or regioselective chemical synthesis which generally comprises reacting a nucleophile and a chiral or prochiral cyclic substrate in the presence of a non-racemic, chiral catalyst to produce a stereoisomerically- and/or regioisomerically-enriched product. The present invention also relates to hydrolytic kinetic resolutions of racemic and diastereomeric mixtures of epoxides.
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