首页> 外国专利> OPTICAL PLASTIC FIBER, OPTICAL FIBER CABLE, OPTICAL FIBER CABLE WITH A CONNECTOR, PROCEDURE FOR THE MANUFACTURE OF A METHYL METHYLLATE POLYMER AND PROCEDURE FOR THE MANUFACTURE OF A PLASTIC OPTICAL FIBER.

OPTICAL PLASTIC FIBER, OPTICAL FIBER CABLE, OPTICAL FIBER CABLE WITH A CONNECTOR, PROCEDURE FOR THE MANUFACTURE OF A METHYL METHYLLATE POLYMER AND PROCEDURE FOR THE MANUFACTURE OF A PLASTIC OPTICAL FIBER.

机译:光学塑料纤维,光学纤维电缆,带有连接器的光学纤维电缆,甲基丙烯酸甲酯聚合物的制造方法以及塑料光学纤维的制造方法。

摘要

Process for the manufacture of a (co) methacrylate polymer which comprises carrying out the polymerization while supplying a monomer (mixture) containing at least 90% by weight in total of at least one methacrylate monomer and an initiator of the radical polymerization represented by formula (II) to a reactor, in which the concentration of the initiator and the polymerization temperature satisfy a ratio represented by equations (1) to (4) and the polymerization temperature is not less than 110 ° C and not exceeding 160 ° C; ln (A) 105, 4 ¿45126 / B (1) ln (A) 2545, 2 / B ¿15, 82 (2) ln (A) 225, 9 ¿102168, 8 / B (3) ln (A) 1300, 0 / B ¿15, 74 (4) in which A is an initiator concentration (a molar ratio of the initiator / monomer); B is a polymerization temperature (ºK); and ln is a symbol for a natural logarithm; wherein R is alkyl or fluoroalkyl.
机译:制备(共)甲基丙烯酸酯聚合物的方法,该方法包括进行聚合反应,同时提供一种单体(混合物),该单体(混合物)的总含量至少为90重量%,其中至少一种是甲基丙烯酸酯单体,并且由式(1)表示的自由基聚合反应的引发剂II)至反应器,其中引发剂的浓度和聚合温度满足由式(1)至(4)表示的比率,并且聚合温度不低于110℃且不超过160℃; ln(A)105,4¿45126 / B(1)ln(A)2545,2 / B¿15,82(2)ln(A)225,9¿102168,8 / B(3)ln(A) 1300,0 / B¿15,74(4)其中A是引发剂浓度(引发剂/单体的摩尔比); B为聚合温度(ºK); ln是自然对数的符号;其中R是烷基或氟代烷基。

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