SILOXANE STAR-GRAFT POLYMERS, CERAMIC POWDERS COATED THEREWITH AND METHOD OF PREPARING COATED CERAMIC POWDERS

摘要

A coated ceramic powder comprises a plurality of ceramic particles and a siloxane star-graft coating polymer encapsulating at least a portion of the particles. The coating polymer comprises Si(w,x,y,z), where w, x, y and z are the mole percent tetrafunctional, trifunctional, difunctional and monofunctional monomeric units, respectively, and wherein w is about 20-100 and x, y and z are about 0-30, 0-50 and 0-10, respectively, and at least one of x, y and z is greater than zero. A method of preparing a coated ceramic powder comprises the steps of (a) polymerizing a tetrafunctional siloxane monomer and at least one of a trifunctional siloxane monomer, a difunctional siloxane monomer and a monofunctional siloxane monomer, (b) adding a quantity of ceramic powder to a reaction vessel, (c) shear mixing the ceramic powder for a time sufficient to wet substantially all of the powder surface, (d) adding the siloxane polymer prepared in step (a) to the reaction vessel containing the shear mixed ceramic powder, (e) shear mixing the shear mixed ceramic powder and the siloxane polymer for a time sufficient to form a siloxane polymer coated ceramic powder, and (f) separating the coated ceramic powder from the components remaining in the reaction vessel.