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Process for dezincing galvanized steel

机译:镀锌钢脱锌工艺

摘要

A process for removing zinc from galvanized steel. The galvanized steel is immersed in an electrolyte containing at least about 15% by weight of sodium or potassium hydroxide and having a temperature of at least about 75° C. and the zinc is galvanically corroded from the surface of the galvanized steel. The material serving as the cathode is principally a material having a standard electrode potential which is intermediate of the standard electrode potentials of zinc and cadmium in the electrochemical series. The corrosion rate may be accelerated by (i) increasing the number density of corrosion sites in the galvanized steel by mechanically abrading or deforming the galvanized steel, (ii) heating the galvanized steel to form an alloy of zinc on the surface of the galvanized steel, (iii) mixing the galvanized steel with a material having a standard electrode potential which is intermediate of the standard electrode potentials of zinc and cadmium in the electrochemical series, or (iv) moving the galvanized steel relative to itself and to the electrolyte while immersed in the electrolyte.
机译:从镀锌钢中去除锌的方法。镀锌钢浸入电解质中,该电解质包含至少约15重量%的氢氧化钠或氢氧化钾,并且具有至少约75℃的温度。 C.并且锌从镀锌钢的表面被电腐蚀。用作阴极的材料原则上是具有标准电极电势的材料,该标准电极电势在电化学系列中处于锌和镉的标准电极电势的中间。可以通过(i)通过机械磨损或使镀锌钢变形来增加镀锌钢中腐蚀部位的数量密度,(ii)加热镀锌钢以在镀锌钢表面上形成锌合金来提高腐蚀速率。 (iii)将镀锌钢与标准电极电位在电化学系列中介于锌和镉的标准电极电位中间的材料混合,或(iv)浸​​入时相对于自身和电解液移动镀锌钢在电解质中。

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