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Method for producing aqueous dispersion of latex particles having heterogeneous morphology, latex particles obtained by this method, dispersion, redispersible powder,

机译:具有不均匀形态的胶乳颗粒的水分散体的制造方法,通过该方法获得的胶乳颗粒,分散体,可再分散粉末,

摘要

The invention relates to a process for the preparation of aqueous dispersions of latex particles having a heterogeneous morphology by a semicontinuous emulsion polymerization, comprising the emulsion polymerizing of ethylenically unsaturated (co)monomers, accompanied by, the addition of cationic and/or anionic and/or nonionic emulsifiers and/or protective colloids as stabilizers, which are directly used as such or synthesized in situ, the semicontinuous emulsion polymerization being performed in the presence of the stabilizer or stabilizers with a monomer mixture, which a) contains at least one nonionic, ethylenically unsaturated monomer with a glass transition temperature Tg above about 30° C. in a quantity of about 10 to 70 wt. %, based on the total weight of ethylenically unsaturated (co)monomers and b) at least one hydrophilic, ethylenically unsaturated monomer in a quantity of about 5 to 30 wt. %, based on the total weight of ethylenically unsaturated (co)monomers.
机译:本发明涉及通过半连续乳液聚合制备具有非均相形态的胶乳颗粒的水分散体的方法,该方法包括烯键式不饱和(共)单体的乳液聚合,同时加入阳离子和/或阴离子和/或直接使用或原位合成的非离子型乳化剂或非离子型乳化剂和/或保护性胶体作为稳定剂,在一种或多种稳定剂与单体混合物的存在下进行半连续乳液聚合,其中a)包含至少一种非离子型,玻璃化转变温度Tg高于约30℃且含量为约10至70重量%的烯属不饱和单体。基于烯键式不饱和(共)单体的总重量和b)的至少1wt。%,至少一种亲水性,烯键式不饱和单体的量为约5至30wt。%。 %,基于烯键式不饱和(共)单体的总重量。

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