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2-Hydroxyphenyl-s-triazine crosslinkers for polymer networks

机译:用于聚合物网络的2-羟基苯基-s-三嗪交联剂

摘要

Compounds of the general formula I′ embedded imagein which R1 is H, C1-C12alkyl; C5-C12cycloalkyl; C2-C18alkyl which is interrupted by one or more O; SR4; OR5; or is a group of formula II or III embedded imageR2, R21 and R3 independently of one another, are H or —Y-T as defined in claim 1, where T is a reactive group selected from OH, acryl- and methacryloxy and arylcarbonate groups, and further symbols are as defined in claim 1, are effective as crosslinking agents for polymeric networks, especially as in flexographic printing plates, coatings, and plastic containers or films. Further provided is a method of protecting the content of a clear or lightly colored plastic container or film against the deleterious effects of ultraviolet radiation, which method comprises permanently and covalently bonding one or more UV absorbing moieties of a durable s-triazine UV absorber via condensation to a suitable polymer component.
机译:通式I'的化合物 “嵌入式图像” 在其中 R 1 是H,C 1 -C 12 烷基; C 5 -C 12 环烷基;被一个或多个O中断的C 2 -C 18 烷基; SR 4 ; OR 5 ;或为一组式II或III <图像alt =“嵌入式图像” file =“ US20050075465A1-20050407-C00002.GIF” he =“ 59.44mm” id =“ EMI-C00002” imgContent =“ chem” imgFormat =“ GIF” wi =“ 69.85mm” /> R 2 ,R 21 和R 3 彼此独立地是如权利要求 1所定义的H或-YT,其中T是选自OH,丙烯酸的反应性基团-和甲基丙烯酰氧基和碳酸芳基酯基团,以及在 1中定义的其他符号,作为聚合物网络的交联剂是有效的,尤其是在柔性版印刷版,涂料和塑料容器或薄膜中。还提供了一种保护透明或浅色塑料容器或薄膜的内容物免受紫外线辐射有害影响的方法,该方法包括通过冷凝作用将一种或多种耐用的s-三嗪紫外线吸收剂的一个或多个紫外线吸收部分永久和共价键合。制成合适的聚合物组分。

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