首页> 外国专利> Alcohol Derivative of 2,6 - dihalo - 4 - (2,3 - Dichloro - allyloxy) - benzyl Insecticides and acaricides that have Properties

Alcohol Derivative of 2,6 - dihalo - 4 - (2,3 - Dichloro - allyloxy) - benzyl Insecticides and acaricides that have Properties

机译:2,6-二卤代-4-(2,3-二氯-烯丙氧基)-苄基杀虫剂和杀螨剂的醇衍生物

摘要

This refers to alcohol Derivatives of 4 - (2,6 - dihalo - 2.3 - Dichloro - (allyloxy) that have Properties of Insecticides and acaricidesA process for the preparation and use of these Compounds; Pesticide compositions in which the active ingredient has been selected Among these Compounds; or a Salt thereof can be used from the point of view of Agrochemical; a process for the preparation and use of such composition Is the material; propagation of Plants treated with these compositions and a method for control;Home pests.Claim 1: a compound of the formula (1): in which A1 and A2 are independently a Link, alquileno C1 - 6, alquenileno C2 or C2 - 6 - 6 alquinileno without replacing or being replaced by six times, each independently of the others,Cycloalkyl with 8 or haloalquilo C1 - C3 - 3; or a Ring of formula (2) in which the links are indicated by - connections with the structural Parts W and T or t and q respectively, and RU and RV together are alquileno C2 - 6; A3 is alquileno C1 - 6 alquenileno, C2 or C2 - 6 - 6 alquinileno Without replacing or being replaced by six times,Each one of them independently of the others, cycloalkyl or haloalquilo C1 - C3 - 8; 3 is nr7, or W, S, - C (= o) - o, - or - C (= o) -, - or - C (= o) - nr8 -, - C (- nr8 = O) - O -, - nr8 - C (= o) - nr8 -, - C (= o) - NH - nr8 - or - nr8 - NHC (= o) - t is a Link, or nr7, NH, S, so, SO2, - C (= o) - or - - or - C (= o) -, - C (= o) - O - - nr8 nr8 - C (= o) -; or Is a Ring of 5 to 6 members, saturated or unsaturated,It contains one to three heteroatoms selected from o, s and N, which is not replaced or substituted alkyl C1 - 6 and which are linked to the adjacent groups A1 and A2 through C Atoms of the Ring; Q is a Link, or, nr7, S, so, or SO2; and or, nr7, S, so, or SO2; x1 and x2, Independently represent F, CL, Br or I; r1 is Halogen, Nitro alkyl C1, - CN, - 6Haloalquilo C1 - 6 - 6, alquilcarbonilo C1, C2 C2 haloalquenilo alquenilo - 6 - 6, 6 - alkoxy alquinilo C2, C1 - 6 - 6, haloalcoxi C1, C2 C2 haloalqueniloxi alqueniloxi - 6, - 6, - 6 alcoxicarbonilo alquiniloxi C2, C1 or C2 - 6 - 6 haloalqueniloxi; R2 and R3 are regardless of I H, halogen, Nitro, alqui CN The haloalquilo C1 C1 - 6, - 6, - 6 alquenilo alquilcarbonilo C1, C2 - 6, 6 - alquinilo haloalquenilo C2, C2 - 6Alkoxy haloalcoxi C1 C1 - 6, - 6, - 6 haloalqueniloxi alqueniloxi C2, C2 - 6 - 6, alquiniloxi C2, C1 or C2 haloalqueniloxi alcoxicarbonilo - 6 - 6; where the substituents R3 are independent of each other when M = 2; R7 is H, alkyl - 6 - cho, C1, C1 haloalquilo - 3 haloalquilcarbonilo C1, C1 - 6 - 3, alkoxyalkyl esters, alq Uilcarbonilo C1 - 6, 6 alcoxicarbonilo C1 - C3 or cycloalkyl - 8; R8 is H, alkyl haloalquilo C1 C1 - 6 - 3Haloalquilcarbonilo C1 - 3 - 6 alquilcarbonilo alkoxyalkyl esters, C1, C1 - C3 - 6, 8 or cycloalkyl benzyl; M is 1 or 2; and is alkyl and cycloalkyl C3 C1 - 6, - 8, - 6 haloalquilo C1, heterociclilo saturated or unsaturated aryl or aryl rings; where and are heterociclilo without replacing or on the basis of the po COMPONENT replacement, replaced a five times;Each one of them independently of the other, with Halogen, - Oh, - NH2, - CN, Nitro alkyl haloalquilo C1 C1 - 6, - 6, - 6 alquilcarbonilo C1, C2 is alquenilo 6 is replaced with or without replacing Halogen, - cn and C2 benzoyl alquinilo alkoxy - 6; C1 - 6, 6 - haloalcoxi Alquiltio C1, C1 - 6 h Aloalquiltio C1 - C2 - alqueniloxi 6, 6, 6 alquiniloxi haloalqueniloxi C2, C1 - C2 - 6, alcoxicarbonilo 6Haloalqueniloxi haloalquilo C1 - C2 - 6, 6 - ariloxi R9, aryl, aryl, or - CH2 -, aminoarilo, heterociclilo, heterocicliloxi - CH2 -, - or - alkyl or aryl heterociclilo C1 - 6; or replacing along two adjacent Ring Atoms of CH2 -, - or - or - or - or - CF2 - or - Where It is possible that the latter groups do INo: ariloxi, aryl, aryl - or - CH2 -, aminoarilo, heterociclilo, heterocicliloxi,- or - CH2 - aryl - and alkyl heterociclilo C1 - 6, without replacing or being replaced with one to three substituents selected, each independently of the others, halogen, Nitro, - CN, - 6 haloalquilo C1 alkyl, alkoxy C1 C1 - 6, - 6, - 6 and haloalcoxi Alquiltio C1 C1 - 6; R9 is - C (= nor10) - Lquilo C1 - 6 and R10 is C1 - 6 h, alkyl, cycloalkyl alkyl C1 - C3 - 6 6Alquenilo alquinilo C2 or C2 - 6 - 6; and, where appropriate, possible isomers and / z / Z, e isomers mixtures and / or tautu00f3meros them, in each case in free form or in Salt form, provided that e is not pirid thiocyanatoacetate, that is Cf3 substituted in position 4 with and without replacing or s Ustituido with Halogen at position 6, when A3 is n o n - butylene pentylene, W is or, R1 and R2 are CLM is 0, and is or, x1 and x2 are CL, and A1, A2, T and q are links.
机译:这是指具有杀虫剂和杀螨剂特性的4-(2,6-二卤代-2.3-二氯-(烯丙氧基)的醇衍生物制备和使用这些化合物的方法;已从中选择活性成分的农药组合物从农业化学的角度来看,可以使用这些化合物;或其盐;制备和使用该组合物的方法是材料;用这些组合物处理过的植物的繁殖及其防治方法;家庭害虫。1 :具有化学式(1)的化合物:其中A1和A2独立地为链环,alquileno C1-6,alquenileno C2或C2-6-6 alquinileno未被取代或被六次取代,各自独立于彼此,环烷基具有8或卤代基C1-C3-3;或式(2)的环,其中的连接由-分别表示与结构部分W和T或t和q的连接,而RU和RV一起为alquileno C2-6 ; A3是Alquileno C1-6 Alquenileno,C2或C2-6-6 alquinileno没有被取代或被六次取代,它们中的每一个独立于另一个,环烷基或卤代烷基C1-C3-8; 3是nr7,或W,S,-C(= o)-o,-或-C(= o)-,-或-C(= o)-nr8-,-C(-nr8 = O)-O -,-nr8-C(= o)-nr8-,-C(= o)-NH-nr8-或-nr8-NHC(= o)-t是一个链接,或nr7,NH,S,so,SO2 ,-C(= o)-或--或-C(= o)-,-C(= o)-O--nr8 nr8-C(= o)-;或者是5到6元的饱和或不饱和成员的环,它包含1-3个选自o,s和N的杂原子,该杂原子未被取代或取代的烷基C1-6并与相邻的A1和A2基团相连环的C原子; Q是一个Link,或为nr7,S,so或SO2;和,或,nr7,S,so或SO2; x1和x2,分别代表F,CL,Br或I; r1是卤素,硝基烷基C1,-CN,-6卤代喹啉C1-6-6,alquilcarbonilo C1,C2 C2卤代alquenilo alquenilo-6-6,6-烷氧基Alquinilo C2,C1-6-6,卤代烷氧基C1,C2 C2卤代烷氧基Alqniloxixi -6,-6,-6 alcoxicarbonilo alquiniloxi C2,C1或C2-6-6卤代喹啉基; R2和R3不考虑IH,卤素,硝基,alqui CN CN卤代alquilo C1-6--6-6-alquenilo alquilcarbonilo C1,C2-6,6-alquinilo haloalquenilo C2,C2-6烷氧基卤代alcoxi C1 C1-6,- 6,-6个卤代烷烃alqueniloxi C2,C2-6-6,alquiniloxi C2,C1或C2的卤代烷烃alcoxicarbonilo-6-6;当M = 2时,取代基R 3彼此独立; R7是H,烷基-6-cho,C1,C1卤代喹啉基-3,卤代芳基碳基C1,C1-6-3,烷氧基烷基酯,Uilcarbonilo C1-6、6,alcoxicarbonilo C1-C3或环烷基-8; R8为H,烷基卤代烷基C1至C1-6-3卤代羰基C1-3至6-6烷碳烷基烷氧基烷基酯,C1,C1至C3-6、8或环烷基苄基; M为1或2;且为烷基和环烷基的C 3 -C 6-,-8-,-6卤代alquilo C 1,杂环基饱和或不饱和的芳基或芳基环;其中和是未取代或在po组分取代的基础上的异环取代,进行了五次取代;其中每一个独立于另一个,用卤素,-OH,-NH2,-CN,硝基烷基卤代alquilo C1 C1-6- -6,-6个alquilcarbonilo C1,C2被alquenilo 6取代或不取代卤素,-cn和C2苯甲酰基alquinilo烷氧基-6; C1-6-6-卤代alloticio C1,C1-6 h Aloalquiltio C1-C2-alqueniloxi 6,6,6 alquiniloxi haloalqueniloxi C2,C1-C2-6,alcoxicarbonilo 6卤代alqueniloxi haloalquilo C1-C2-6,6,6-ariloxi R9 ,芳基或-CH 2-,氨基芳基,杂环基,杂环基-CH 2-,-或-烷基或芳基杂环基C 1-6;或沿着CH2的两个相邻环原子进行取代-,-或-或-或-或-CF2-或-当后一个基团可能具有INo时:ariloxi,芳基,芳基-或-CH2-,氨基芳基,杂环基,杂环基,-或-CH 2-芳基-和烷基杂环基C1-6,而不是被取代或被1-3个选择的取代基所取代,每个取代基彼此独立,卤素,硝基,-CN,-6卤代喹啉C1烷基,烷氧基C1C1 -6,-6,-6和haloalcoxi Alquiltio C1 C1-6; R9是-C(= nor10)-Lquilo C1-6,并且R10是C1-6h,烷基,环烷基烷基C1-6-C3-6 6 Alquenilo alquinilo C2或C2-6-6;以及在适当情况下可能的异构体和 / z / Z,e异构体混合物和 /或taut u00f3meros混合物,在每种情况下均为游离形式或盐形式,但前提是e不是非硫代氰基乙酸乙酸酯,即被Cf3取代在位置4处,是否在位置6处用卤素取代或不使用s或UStituido取代,当A3为非丁烯戊烯,W为或,R1和R2为CLM为0,且为或时,x1和x2为CL,以及A1,A2 ,T和q是链接。

著录项

  • 公开/公告号AR042649A1

    专利类型

  • 公开/公告日2005-06-29

    原文格式PDF

  • 申请/专利权人 SYNGENTA PARTICIPATIONS AG;

    申请/专利号AR2003P104774

  • 发明设计人

    申请日2003-12-22

  • 分类号C07C69/78;C07C43/225;C07C205/06;C07C275/34;C07D317/26;C07D317/52;C07D215/26;C07D239/42;C07D285/08;A01N25/02;A01N25/12;A01N29/00;A01N31/00;

  • 国家 AR

  • 入库时间 2022-08-21 22:18:48

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