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NON-CONJUGATED CYCLIC DIENE, NON-CONJUGATED CYCLIC DIENE COMPOSITION AND METHOD OF PRODUCING POLYMER BASED ON NON-CONJUGATED CYCLIC DIENE

机译:非共轭环二烯,非共轭环二烯的组成及基于非共轭环二烯的聚合物的制备方法

摘要

NON-CONJUGATED CYCLIC DIENE, NON-CONJUGATED CYCLIC DIENE COMPOSITION AND METHOD OF PRODUCING POLYMER BASED ON NON-CONJUGATED CYCLIC DIENEABSTRACT OF THE DISCLOSUREIt is an object of the present invention to provide a non-conjugated cyclic diene and a non-conjugated cyclic diene composition which enable the production of a polymer based on non-conjugated cyclic diene which makes it possible to produce a (co)polymer at a high degree of polymerization activity, and a method of producing a polymer based on non-conjugated cyclic diene which makes it possible to produce a (co)polymer at a high degree of polymerization activity. A non-conjugated cyclic diene is used which meets at least one of the following requirements: (1) it contains a compound having a seven-membered cyclic triene hydrocarbon structure in a specific amount or less and (2) it contains a conjugated polyene compound having an eight-membered bicyclic hydrocarbon structure in a specific amount. Also, in a method of producing a non-conjugated cyclic diene polymer, the aforementioned non-conjugated cyclic diene is supplied to the polymerization or copolymerization using an olefin polymerization catalyst containing an organic aluminum oxy compound and/or an ionizing ionic compound. Also, in another method of producing a non-conjugated cyclic diene polymer, a non-conjugated cyclic diene which is obtained by bringing a crude non-conjugated cyclic diene into contact 60 with an alkali and then removing at least a part of a low-boiling point fraction and at least a part of a high-boiling point fraction is used for the Polymerization.
机译:非共轭环二烯,非共轭环二烯基于非缩聚物的聚合物的组成和制备方法共轭二烯披露摘要本发明的一个目的是提供非共轭环状二烯和非共轭环状二烯组合物,其使得能够生产基于非共轭环状二烯的聚合物,这使得有可能在以下条件下生产(共)聚合物。高度聚合活性和基于非共轭环状二烯的聚合物的制备方法,使得可以以高聚合活性制备(共)聚合物。使用满足以下条件中的至少一项的非共轭环状二烯:(1)在特定条件下含有具有七元环状三烯烃结构的化合物。(2)以特定的量含有具有八元双环烃结构的共轭多烯化合物。另外,在制备非共轭环状二烯聚合物的方法中,将上述非共轭环状二烯供应至使用包含有机铝氧基化合物和/或电离离子化合物的烯烃聚合催化剂进行聚合或共聚。同样,在生产非共轭环状二烯聚合物的另一种方法中,非共轭环状二烯是通过使粗制非共轭环状二烯与碱接触60,然后除去至少一部分低价环烯而得到的。沸点馏分和高沸点馏分的至少一部分用于聚合。

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