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COMPOSITION COEXTRUDABLE WITH PVDF, DOES NOT EXHIBIT WHITENING UNDER STRESS

机译:可与PVDF共挤出的组合物,在应力下不白化

摘要

The present invention relates to a composition coextrudable with PVDF and comprising: .cndot. 30 to 50 parts of PVDF, .cndot. 70 to 50 parts of a copolymer (A) comprising, by weight, 90 to 50% of methyl methacrylate (MMA) for respectively 10 to 50% of an alkyl (meth) acrylate, the alkyl having from 2 to 24 carbon atoms, .cndot. 1 to 4 parts of a UV absorber, .cndot. the total making 100 parts. The invention also relates to coextruded films consisting of .cndot. a layer of the above coextrudable composition (also called the adhesive layer) and directly attached thereto, .cndot. a PVDF-based layer comprising as main constituents from 50 to 100 parts of PVDF per 50 to 0 parts of PMMA (this layer is also called for simplification "PVDF layer"). These films have sufficient mechanical properties to allow ur manipulation, their implementation and their use as a coating transparent to visible light but opaque to UV radiation. The composition of the adhesive layer is based on the use of a polymethyl methacrylate copolymerized with a flexible acrylate making it possible to obtain a binder formulation having a compromise of properties between the transparency of the film, its good mechanical strength and its ability not to bleach when subjected to significant deformation.
机译:本发明涉及可与PVDF共挤出的组合物,其包含:.cndot。 PVDF的30至50份。 70至50重量份的共聚物(A),其包含按重量计分别为10至50%的(甲基)丙烯酸烷基酯的90至50%的甲基丙烯酸甲酯(MMA),该烷基具有2至24个碳原子。 cndot。紫外线吸收剂1-4点。总共制作了100个零件。本发明还涉及由.cndot组成的共挤出膜。上述可共挤出组合物的一层(也称为粘合层),并直接附着在其上。每50至0份PMMA包含50至100份PVDF作为主要成分的基于PVDF的层(该层也被称为简化的“ PVDF层”)。这些薄膜具有足够的机械性能,可以进行操作,实施和用作对可见光透明但对UV辐射不透明的涂层。粘合剂层的组成基于使用与柔性丙烯酸酯共聚的聚甲基丙烯酸甲酯,这使得可以获得在薄膜的透明性,其良好的机械强度和其不漂白能力之间折衷的粘合剂配方。发生明显变形时。

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