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MOLYBDENUM-MODIFIED VANADIUM-PHOSPHORUS OXIDE CATALYSTS FOR THE PRODUCTION OF MALEIC ANHYDRIDE

机译:钼改性的钒磷氧化物催化剂用于生产马来酸酐

摘要

An active catalyst having a crystal structure corresponding to that of a catalyst that has been prepared and activated by the following process. A substantially pentavalent vanadium-containing compound is reacted with a pentavalent phosphorus-containing compound in an alcohol medium capable of reducing the vanadium to an oxidiation state of less than +5. Molybdenum is incorporated into the product of the reaction, thereby forming a solid molybdenum-modified precursor composition. The alcohol is removed to produce a dried solid molybdenum-modified precursor composition. Shaped bodies comprising said dried solid molybdenum-modified precursor composition are formed. The dried formed molybdenum-modified catalyst precursor composition is activated to transform it into the active catalyst.
机译:具有与通过以下方法制备和活化的催化剂的晶体结构相对应的晶体结构的活性催化剂。在能够将钒还原至小于+5的氧化态的醇介质中,使基本上五价的含钒化合物与五价的含磷化合物反应。将钼掺入反应产物中,从而形成固体钼改性的前体组合物。除去醇以产生干燥的固体钼改性的前体组合物。形成包含所述干燥的固体钼改性的前体组合物的成形体。将干燥的形成的钼改性的催化剂前体组合物活化以将其转化成活性催化剂。

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