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FLAME-RETARDANT MODIFIED PHOSPHOROUS COPOLYESTER, THE USE AND METHOD FOR THE PRODUCTION THEREOF

机译:阻燃改性磷共聚体,其用途和生产方法

摘要

The invention relates to a flame-retardant modified phosphorous copolyester whose phosphorus content ranges from 5 to 7 mass % and which is obtainable by esterificating at least one type of dicarboxylic acid with at least one type of diol and/or by transestereficating at least one type of dicarboxylic acid diester with at least one type of diol in the presence of one bifunctional flame-retardant additive compound DOP and at least one another phosphorous bifunctional additive compound which is different from the bifunctional DOP additive compound, and afterwards by polycondensating the thus generated products ether during the generation by esterificating and/or transestereficating. Said additive compound DOP supplies up to 3.5 mass % of a total phosphorus content whereas the rest of the total phosphorus content is supplied by the other bifunctional phosphorous compound. Said invention also relates to the inventive method for producing the flame-retardant modified phosphorous copolyester and the use thereof in the form of a master batch, in particular for producing polyester fibres whose total phosphorus content ranges from 0.4 to 0.7 mass %.
机译:本发明涉及一种阻燃改性的磷共聚酯,其磷含量为5至7质量%,并且可以通过将至少一种二羧酸与至少一种二醇酯化和/或通过酯交换至少一种来获得。在一种双官能阻燃添加剂化合物DOP和至少一种不同于双官能DOP添加剂化合物的另一种磷双官能添加剂化合物的存在下,将二羧酸二酯与至少一种二醇混合,然后将所得产物缩聚通过酯化和/或酯交换反应生成醚。所述添加剂化合物DOP提供最高3.5质量%的总磷含量,而其余的总磷含量由另一种双官能磷化合物提供。所述发明还涉及本发明的用于制备阻燃改性的磷共聚酯的方法及其以母料的形式的用途,特别是用于生产总磷含量为0.4至0.7质量%的聚酯纤维。

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