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SELENOPHOSPHINIC AMIDES, SELENOPHOSPHORIC AMIDES, SELENOPHOSPHORIC CHLORIDES, AND PROCESSES FOR PRODUCTION OF THEM
SELENOPHOSPHINIC AMIDES, SELENOPHOSPHORIC AMIDES, SELENOPHOSPHORIC CHLORIDES, AND PROCESSES FOR PRODUCTION OF THEM
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机译:亚硒酰胺,亚硒酰胺,亚硒酰氯及其生产方法
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摘要
Selenophosphinic amides having structures represented by the general formula (1); selenophosphoric amides having structures represented by the general formula (4); and selenophosphoric chlorides having structures represented by the general formula (7) which may take (R)- or (S)-configuration, wherein Ph is phenyl; R1 and R2 are each alkyl; R3 is hydrogen or alkyl; at least either of R2 and R3 is chiral alkyl; R4 and R8 are each hydrogen, halogeno, alkyl, aryl, alkoxy, or silyl; R5 is -NR6R7 or alkylpiperidyl; R6 is hydrogen or alkyl; and R7 is alkyl.
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机译:具有由通式(1)表示的结构的硒代次膦酰胺;具有由通式(4)表示的结构的硒代磷酸酰胺;具有由通式(7)表示的结构的硒代磷酰氯化物,其可以具有(R)-或(S)-构型,其中Ph是苯基; R1和R2各自为烷基; R3是氢或烷基; R2和R3中至少一个是手性烷基; R4和R8各自为氢,卤代,烷基,芳基,烷氧基或甲硅烷基; R5是-NR6R7或烷基哌啶基; R6是氢或烷基; R 7为烷基。
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