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COMPOSITION FOR POLYURETHANE ELASTOMER HAVING HIGH HARDNESS AND EXCELLENT ABRASION RESISTANCE

机译:具有高硬度和出色耐磨性的聚氨酯弹性体组合物

摘要

A composition is provided for preparing a polyurethane elastomer, which is of high hardness and excellent abrasion resistance. The composition comprises a urethane prepolymer with an unreacted isocyanate content of 5-22% by weight, made from the reaction of a mixture of an aromatic diisocyanate and a cycloaliphatic diisocyanate in weight proportions of 1: 0.1 to 1: 5 with a polyol having a weight average molecular weight of 200-3,000; and a curing system comprising a mixture of an aromatic amine and an alcohol in weight proportions of 1: 0.3 to 1: 3, said alcohol comprising a multifunctional alcohol and a polyol, wherein, when the equivalent ratio between the prepolymer and the curing system is set as 100 in terms of index, they are mixed in the index range of about 70 to 200. The prepolymer is suitably controlled in viscosity and reactivity as to provide effective workability. Also, a curing system improves the hardness and abrasion resistance properties of finally produced polyurethane elastomers and allows the reactivity with prepolymer to be controlled with higher ease than dose a curing system composed of an aromatic amine alone.
机译:提供了一种用于制备聚氨酯弹性体的组合物,该组合物具有高硬度和优异的耐磨性。该组合物包含未反应的异氰酸酯含量为5-22重量%的氨基甲酸酯预聚物,其由芳族二异氰酸酯和脂环族二异氰酸酯的重量比为1:0.1至1:5的混合物与具有重均分子量为200-3,000;包含芳族胺和醇的重量比为1:0.3至1:3的混合物的固化体系,所述醇包括多官能醇和多元醇,其中当预聚物与固化体系之间的当量比为以指数计为100,将它们在约70至200的指数范围内混合。适当控制预聚物的粘度和反应性以提供有效的可加工性。而且,与单独使用由芳族胺组成的固化体系相比,固化体系改善了最终生产的聚氨酯弹性体的硬度和耐磨性,并使得与预聚物的反应性更易于控制。

著录项

  • 公开/公告号EP1472299A4

    专利类型

  • 公开/公告日2005-04-20

    原文格式PDF

  • 申请/专利权人 SKC CO. LTD.;

    申请/专利号EP20030703496

  • 发明设计人 LEE JONGMYUNG;SHIN JUNGHWAN;PARK INHA;

    申请日2003-02-04

  • 分类号C08G18/32;C08G18/10;C08G18/48;C08G18/50;C08G18/72;

  • 国家 EP

  • 入库时间 2022-08-21 22:08:50

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