DOUBLE metal cyanide catalyst METHOD FOR PRODUCING DOUBLE metal cyanide catalyst and process produce polyols

摘要

1. double u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du044bu0439 catalyst having the formula;u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 where m1 is at least one metal sa;m2 u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 an at least one metal cyanide salt.;m3 u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 along at least one of a transition metal salt.;the m4 u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 along at least one alkali metal salt.;l1 u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 a, at least one organic u043au043eu043cu043fu043bu0435u043au0441u043eu043eu0431u0440u0430u0437u0443u044eu0449u0438u0439 ligand;;l2 u00a0u0432u043bu00a0u0435u0442u0441u00a0 u043du0435u043eu0431u00a0u0437u0430u0442u0435u043bu044cu043du044bu043c and can u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0442u044c along at least one u0444u0443u043du043au0446u0438u043eu043du0430u043bu0438u0437u0438u0440u043eu0432u0430u043du043du044bu0439 polymer, and;x, u04451, and z u00a0u0432u043bu00a0u044eu0442u0441u00a0 by integers and u0432u044bu0431u0438u0440u0430u044eu0442u0441u00a0 so as to ensure the u044du043bu0435u043au0442u0440u043eu043du0435u0439u0442u0440u0430u043bu044cu043du043eu0441u0442u044c dual u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du043eu0433u043e catalyst.;2. double u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du044bu0439 catalyst for 1, in which the salt of metal u00a0u0432u043bu00a0u0435u0442u0441u00a0 zinc chloride.;3. double u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du044bu0439 catalyst for 1, in which the salt u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u0430 u00a0u0432u043bu00a0u0435u0442u0441u00a0 u0433u0435u043au0441u0430u0446u0438u0430u043du043eu043au043eu0431u0430u043bu044cu0442u0430u0442 u043au0430u043bu0438u00a0 (iii).;4. double u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du044bu0439 catalyst for 1, in which the organic u043au043eu043cu043fu043bu0435u043au0441u043eu043eu0431u0440u0430u0437u0443u044eu0449u0438u043c u043bu0438u0433u0430u043du0434u043eu043c u00a0u0432u043bu00a0u0435u0442u0441u00a0 tert. butanol.;5. double u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du044bu0439 catalyst for 1, in which the alkali metal salt of u00a0u0432u043bu00a0u0435u0442u0441u00a0 u043au0430u043bu0438u00a0 chloride, chloride u043du0430u0442u0440u0438u00a0, u043du0430u0442u0440u0438u00a0 bromide, chloride or bromide u043bu0438u0442u0438u00a0 u043bu0438u0442u0438u00a0.;6. double u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du044bu0439 catalyst for 1, in which u0444u0443u043du043au0446u0438u043eu043du0430u043bu0438u0437u0438u0440u043eu0432u0430u043du043du044bu0439 polymer u0441u043eu0434u0435u0440u0436u0438u0442u0441u00a0 quantity ranging from about 2 to about 98% of the total mass of hv mas. u043eu0439u043du043eu0433u043e u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du043eu0433u043e catalyst.;7. double u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du044bu0439 catalyst on p.1, in which the polymer u0444u0443u043du043au0446u0438u043eu043du0430u043bu0438u0437u0438u0440u043eu0432u0430u043du043du044bu043c u00a0u0432u043bu00a0u0435u0442u0441u00a0 simple resistant polyester; complex resistant polyester; polycarbonate; u043fu043eu043bu0438u0430u043bu043au0438u043bu0435u043du0433u043bu0438u043au043eu043bu044c - u0441u043eu0440u0431u0438u0442u0430u043du043eu0432u044bu0439 complex ether; a cap u0438u0446u0438u0434u0438u043bu043eu0432u044bu0439 ether u043fu043eu043bu0438u0430u043bu043au0438u043bu0435u043du0433u043bu0438u043au043eu043bu00a0; polyacrylamide; u0430u043au0440u0438u043bu0430u043cu0438u0434u0430 copolymer and acrylic acid copolymer u043fu043eu043bu0438u0430u043au0440u0438u043bu043eu0432u0430u00a0 acid, acrylic acid and u043cu0430u043bu0435u0438u043du043eu0432u043eu0439 kitty copolymer of n - u0432u0438u043du0438u043bu043fu0438u0440u0440u043eu043bu0438u0434u043eu043du0430 lots and acrylic acidcopolymer acrylic acid and styrene and the sa copolymer of maleic anhydride and styrene or u043cu0430u043bu0435u0438u043du043eu0432u043eu0439 acid or their salts; u043fu043eu043bu0438u0430u043au0440u0438u043bu043eu043du0438u0442u0440u0438u043bu044b; u043fu043eu043bu0438u0430u043bu043au0438u043bu0430u043au0440u0438u043b al; u043fu043eu043bu0438u0430u043bu043au0438u043bu043cu0435u0442u0430u043au0440u0438u043bu0430u0442; u043fu043eu043bu0438u0432u0438u043du0438u043bu043cu0435u0442u0438u043bu043eu0432u044bu0439 simple ether; u043fu043eu043bu0438u0432u0438u043du0438u043bu044du0442u0438u043bu043eu0432u044bu0439 simple ether; polyvinyl acetate;;polyvinyl alcohol, poly - n - u0432u0438u043du0438u043bu043fu0438u0440u0440u043eu043bu0438u0434u043eu043d; u043fu043eu043bu0438u0432u0438u043du0438u043bu043cu0435u0442u0438u043bu043au0435u0442u043eu043d; poly (4 - u0432u0438u043du0438u043bu0444u0435u043du043eu043b); polymer u043eu043au0441u0430u0437u043eu043bu0438u043du0430; u043fu043eu043bu0438u0430u043bu043au0438u043bu0435u043du0438u043cu0438u043d; u0433u0438u0434u0440u043eu043au0441u0438u044du0442u0438u043bu0446u0435u043bu043bu044eu043bu043bu043eu0437u0430; u043fu043eu043bu0438u0430u0446u0435u0442u0430u043bu044c; p u0440u043eu0441u0442u043eu0439 u0433u043bu0438u0446u0438u0434u0438u043bu043eu0432u044bu0439 ether; hepatic glycoside; carbon acid with alcohol ether groups; u0436u0435u043bu0447u043du0430u00a0 acid and its saltether or amide; u0446u0438u043au043bu043eu0434u0435u043au0441u0442u0440u0438u043d; u0444u043eu0441u0444u043eu0440u043du043eu0435 connection; the air u043du0435u043du0430u0441u044bu0449u0435u043du043du043eu0439 carbon acid; or u0438u043eu043du043eu0433u0435u043du043du043eu0435 surface active compound or u043cu0435u0436u0444u0430u0437u043du043e - active the connection.;8. double u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du044bu0439 catalyst for 1, in which the alkali metal salt u0441u043eu0434u0435u0440u0436u0438u0442u0441u00a0 in quantities ranging from about 0.4 to about 6% of the total mass of mas. the double m u0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du043eu0433u043e catalyst.;9.method u043fu043eu043bu0443u0447u0435u043du0438u00a0 dual u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du043eu0433u043e catalyst comprising a combination of (i) at least one metal sa (ii) at least one salt u043cu0435u0442u0430u043bu043bu0446u0438 u0430u043du0438u0434u0430; (iii) at least one organic u043au043eu043cu043fu043bu0435u043au0441u043eu043eu0431u0440u0430u0437u0443u044eu0449u0435u0433u043e u043bu0438u0433u0430u043du0434u0430; (iv) at least one alkali metal sa and u043du0435u043eu0431u00a0u0437u0430u0442u0435u043bu044cu043du043e, (v) at least one u0444u0443u043du043au0446u0438u043eu043du0430u043bu0438u0437u0438u0440u043eu0432u0430u043du043du043eu0433u043e polymer in u0443u0441u043bu043eu0432u0438u00a0u0445,sufficient u0434u043bu00a0 u043eu0431u0440u0430u0437u043eu0432u0430u043du0438u00a0 catalyst.;10. method for u00a0u0432u043bu00a0u0435u0442u0441u00a0 p.9, in which the salt of zinc chloride.;11. method for p.9, in which salt u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u0430 u00a0u0432u043bu00a0u0435u0442u0441u00a0 u0433u0435u043au0441u0430u0446u0438u0430u043du043eu043au043eu0431u0430u043bu044cu0442u0430u0442 u043au0430u043bu0438u00a0 (iii).;12. method for p.9, in which organic u043au043eu043cu043fu043bu0435u043au0441u043eu043eu0431u0440u0430u0437u0443u044eu0449u0438u043c u043bu0438u0433u0430u043du0434u043eu043c u00a0u0432u043bu00a0u0435u0442u0441u00a0 tert. butanol.;13. method for p.9, in which alkali metal chloride salt u00a0u0432u043bu00a0u0435u0442u0441u00a0 u043au0430u043bu0438u00a0, u043du0430u0442u0440u0438u00a0 u043du0430u0442u0440u0438u00a0 chloride, bromide, chloride or bromide u043bu0438u0442u0438u00a0 u043bu0438u0442u0438u00a0.;14. method for p.9, which u0444u0443u043du043au0446u0438u043eu043du0430u043bu0438u0437u0438u0440u043eu0432u0430u043du043du044bu0439 polymer used in the number in the range from about 2 to about 98% of the total mass of mas. the dual u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du043eu0433u043e cathal u0438u0437u0430u0442u043eu0440u0430.;15. method for p.9, in which the polymer u0444u0443u043du043au0446u0438u043eu043du0430u043bu0438u0437u0438u0440u043eu0432u0430u043du043du044bu043c u00a0u0432u043bu00a0u0435u0442u0441u00a0 simple resistant polyester; complex resistant polyester; polycarbonate; u043fu043eu043bu0438u0430u043bu043au0438u043bu0435u043du0433u043bu0438u043au043eu043bu044c - u0441u043eu0440u0431u0438u0442u0430u043du043eu0432u044bu0439 complex ether; a cap u0438u0446u0438u0434u0438u043bu043eu0432u044bu0439 ether u043fu043eu043bu0438u0430u043bu043au0438u043bu0435u043du0433u043bu0438u043au043eu043bu00a0; polyacrylamide; u0430u043au0440u0438u043bu0430u043cu0438u0434u0430 copolymer and acrylic acid; u043fu043eu043bu0438u0430u043au0440u0438u043bu043eu0432u0430u00a0 acid; acrylic acid copolymer and u043cu0430u043bu0435u0438u043du043eu0432u043eu0439 kee slots, copolymer of n - vinyl - u043fu0438u0440u0440u043eu043bu0438u0434u043eu043du0430 and acrylic acidpolymer of acrylic acid and styrene and the sa copolymer of maleic anhydride and styrene or u043cu0430u043bu0435u0438u043du043eu0432u043eu0439 acid or their salts; u043fu043eu043bu0438u0430u043au0440u0438u043bu043eu043du0438u0442u0440u0438u043bu044b; u043fu043eu043bu0438u0430u043bu043au0438u043bu0430u043au0440u0438u043bu0430u0442 ; u043fu043eu043bu0438u0430u043b - u043au0438u043bu043cu0435u0442u0430u043au0440u0438u043bu0430u0442; u043fu043eu043bu0438u0432u0438u043du0438u043bu043cu0435u0442u0438u043bu043eu0432u044bu0439 simple ether, u043fu043eu043bu0438u0432u0438u043du0438u043bu044du0442u0438u043bu043eu0432u044bu0439 simple ether, polyvinyl acetate, polyvinyl alcohol, poly - n - u0432u0438u043du0438u043bu043fu0438u0440u0440u043eu043bu0438u0434u043eu043d, u043fu043eu043bu0438u0432u0438u043du0438u043bu043c u0435u0442u0438u043b - ketone, poly (4 - u0432u0438u043du0438u043bu0444u0435u043du043eu043b); polymer u043eu043au0441u0430u0437u043eu043bu0438u043du0430,u043fu043eu043bu0438u0430u043bu043au0438u043bu0435u043du0438u043cu0438u043d; u0433u0438u0434u0440u043eu043au0441u0438u044du0442u0438u043bu0446u0435u043bu043bu044eu043bu043bu043eu0437u0430, u043fu043eu043bu0438u0430u0446u0435u0442u0430u043bu044c; simple u0433u043bu0438u0446u0438u0434u0438u043bu043eu0432u044bu0439 ether; hepatic glycoside; carbon acid with alcohol ether groups; u0436u0435u043bu0447u043du0430u00a0 acid and its aall;ether or amide, u0446u0438u043au043bu043eu0434u0435u043au0441u0442u0440u0438u043d, u0444u043eu0441u0444u043eu0440u043du043eu0435 compound, ether u043du0435u043du0430u0441u044bu0449u0435u043du043du043eu0439 carbon acid or u0438u043eu043du043eu0433u0435u043du043du043eu0435 surface active compound or u043cu0435u0436u0444u0430u0437u043du043e - active the connection.;16. double u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du044bu0439 catalyst, the way to 1, preferably containing at least one alkali metal salt of within from about 0.4 to about 6% of the total mass of mas. the dual u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du043eu0433u043e catalyst.;17. method u043fu043eu043bu0443u0447u0435u043du0438u00a0 u043fu043eu043bu0438u043eu043bu0430 interactions, including (i) at least one source u0441u043eu0435u0434u0438u043du0435u043du0438u00a0 having active hydrogen atoms with (ii) a least one of u043au0441u0438u0434u043eu043c (iii) in the presence of at least one double u043cu0435u0442u0430u043bu043bu0446u0438u0430u043du0438u0434u043du043eu0433u043e catalyst for 1 or of the way in u0443u0441u043bu043eu0432u0438u00a0u0445 p.9, sufficient u0434u043bu00a0 educated u0438u00a0 u043fu043eu043bu0438u043eu043bu0430.