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METHOD FOR PRODUCING middle distillates hydroisomerization and hydrocracking of heavy fractions of the products produced by the process Fischer-Tropsch

机译:生产中间馏分的加氢异构化和加氢裂化的方法是费-托法生产的产物

摘要

1. A method for producing middle distillates from a paraffinic load obtained by Fischer-Tropsch synthesis comprising the following successive steps: a) separation of at least one light fraction boot sole to obtain the so-called heavy fraction with an initial boiling point component 120-200 ° C, b) may hydrotreating said heavy fraction, optionally followed by step (c) removing at least a portion of the water, d) passing at least a portion of said fraction, optionally hydrotreated, through amorphous hydroisomerization catalyst / hydrocracking, and this catalyst conversion products with boiling points above or equal to 370 ° C into products with boiling points below 370 ° C, greater than 80 wt.%, e) distilling hydrocracked / hydroisomerized fractions to obtain middle distillates, and returning to step d ) of the residual fraction boiling above said middle distillyatov.2. A method according to claim 1 in which said light fraction separated and carried on a steam kreking.3. A method according to claim 1 or 2, wherein at least one of kerosene fractions, gas oil of step (e) is partially recycled to step (d) .4. A method according to claim 3, wherein the catalyst phase (d) does not contain additional galogena.5. A method according to claim 4, wherein the catalyst phase (d) is not ftorirovan.6. Installation for producing middle distillates comprising at least one fractionation zone boot produced in a Fischer-Tropsch synthesis, having at least one inlet for input loading, at least one outlet for removing a heavy fraction with an initial boiling point equal to a temperature of 120-200 ° C, and at least one outlet for removing at least one lighter fraction than said heavy fraction, optionally at least one hydrotreatment zone provided with one line for entering the heavy fraction, at least one zone containing a hydrocracking catalyst / hydroisomerisation provided with one connection for inputting at least a portion of the heavy fraction, optionally hydrotreated, the at least one distillation column provided with nozzles for discharging middle distillates and a nozzle for discharging a residual fraction boiling above the middle distillates, at least one line for recycling the residual fraction to the zone containing the catalyst hydrocracking / hydroisomerization of at least one input line for the light fraction in the steam krekinga.7 . Apparatus according to claim 6, comprising at least one line for recycling part of the middle distillyatov.8. Installation according to one of claims 6 or 7, comprising a water separating zone located between zones hydrotreating and hydrocracking / hydroisomerization.
机译:1.一种由通过费-托合成获得的链烷烃负载生产中间馏分的方法,其包括以下连续步骤:a)分离至少一个轻馏分靴底以得到具有初始沸点组分120的所谓重馏分。 -200°C,b)可以对所述重质馏分进行加氢处理,任选地进行步骤(c),除去至少一部分水,d)使至少一部分所述馏分通过无定形加氢异构化催化剂/加氢裂化进行任选加氢处理,并且该催化剂将沸点高于或等于370°C的产物转化为沸点低于370°C,大于80 wt。%的产物,e)蒸馏加氢裂化/加氢异构化的馏分以获得中间馏分,并返回步骤d)沸腾在所述中间distillyatov.2以上的残余馏分。 2.根据权利要求1的方法,其中所述轻馏分分离并进行蒸汽除臭。3。 3.根据权利要求1或2所述的方法,其中将步骤(e)的煤油馏分,粗柴油中的至少一种部分再循环至步骤(d).4。 4.根据权利要求3所述的方法,其中,所述催化剂相(d)不包含额外的致热剂。 5.根据权利要求4所述的方法,其中,所述催化剂相(d)不是甲苯磺隆。用于生产中间馏分的设备,其包括至少一个在费-托合成中生产的分馏区塔罩,具有至少一个用于输入负载的入口,至少一个用于去除初始沸点等于120°C的重馏分的出口。 200℃,以及至少一个用于除去至少一种比所述重馏分轻的馏分的出口,任选地,至少一个加氢处理区设有一条进入重馏分的管线,至少一个含有加氢裂化催化剂/加氢异构化的区设有一个用于输入至少一部分重质馏分的接口,该重馏分至少进行了加氢处理,该至少一个蒸馏塔设有用于排出中间馏出物的喷嘴和用于排出沸腾在中间馏出物上方的残留馏分的喷嘴,至少一条用于回收残留物的管线含有至少一个i的催化剂加氢裂化/加氢异构化区域的馏分蒸汽krekinga中轻馏分的输入线。7。 7.根据权利要求6所述的设备,包括至少一条用于回收中间distillyatov.8的一部分的管线。 8.根据权利要求6或7之一的设备,其包括位于加氢处理和加氢裂化/加氢异构化区域之间的水分离区域。

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