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Acryloxypropyl - or methacryloxypropyl - groups containing siloxane - oligomers, processes for their preparation and their use

机译:含丙烯酰氧基丙基或甲基丙烯酰氧基丙基的硅氧烷-低聚物,其制备方法和用途

摘要

Mixture of lacunar and cyclic siloxane - oligomers of the general formulae i and ii, in which the substituents r of 3 - methacryloxypropyl - or 3 - acryloxypropyl - groups - and methoxy, ethoxy - and / or propoxy - groups and, if appropriate, alkyl -, fluoroalkyl -, - isoalkyl, cycloalkylmit 1 to 18 c - atoms and / or aryl - groups having 6 to 12 c - atoms to a silicon - atom at most one 3 - methacryloxypropyl - or 3 - acryloxypropyl - group is bound and the degree of oligomerization of compounds of the general formula i in the range from 2 & m & 25 and the for compounds of the general formula ii in the range from 2 ≦ n ≦ 8 and the quotient of the molar ratio of si / alkoxy - grouping is ≧ 0,5.
机译:腔隙式和环状硅氧烷的混合物-通式i和ii的低聚物,其中3-甲基丙烯酰氧基丙基-或3-丙烯酰氧基丙基-以及甲氧基,乙氧基和/或丙氧基-以及(如果合适)烷基的取代基-,氟烷基-,-,异烷基,环烷基具有1至18个c-原子和/或与硅原子具有6至12个c-原子的芳基-至多一个1-甲基-丙烯酰氧基丙基或3-丙烯酰氧基丙基结合并且通式i的化合物的低聚度为2≤n≤1。 m& 25和通式ii的化合物在2≤n≤8的范围内,并且si /烷氧基-基团的摩尔比的商为≥0.5。

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