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Method for maintaining the acidic catalytically active sites in sapo molecular sieves.

机译:维持sapo分子筛中酸性催化活性位点的方法。

摘要

This invention is directed to a molecular sieve having acid catalyst sites and a method of maintaining the acid catalyst sites of a template-containing silicoaluminophosphate molecular sieve. The method comprises providing a template-containing silicoaluminophosphate molecular sieve and heating the molecular sieve in an oxygen depleted environment under conditions effective to maintain or preserve the number of acid catalyst sites. The heated molecular sieve exhibits at least one peak in the infrared region in a range of from 3630 cm-1 to 3580 cm-1. Preferably, the heated molecular sieve exhibits a combined peak area in the 3630 cm-1 to 3580 cm-1 range of at least 10 % of a total peak area of all peaks in an infrared region between 4000 cm-1 to 3400 cm-1.
机译:本发明涉及具有酸催化剂位点的分子筛,以及维持含模板的硅铝磷酸盐磷酸分子筛的酸催化剂位点的方法。该方法包括提供含模板的硅铝磷酸盐分子筛,并在有效维持或保持酸催化剂位点数量的条件下在贫氧环境中加热分子筛。加热的分子筛在红外区域中显示至少一个峰,其范围为3630 cm-1至3580 cm-1。优选地,加热的分子筛在3630cm-1至3580cm-1范围内表现出组合峰面积,其在4000cm-1至3400cm-1之间的红外区域中的所有峰的总峰面积的至少10%。 。

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