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Active carbon with high resistance to crushing, useful as catalyst, catalyst support, particularly for oxidizing mercaptans to disulfides, or selective adsorbants

机译:具有高抗粉碎性的活性炭,可用作催化剂,催化剂载体,特别是用于将硫醇氧化为二硫化物或选择性吸附剂

摘要

Active carbon (A) has total pore volume at least 1, preferably 1.2, ml/g; bed resistance (in the Shell bulk crushing test) at least 1, preferably 1.7, MPa, and BET surface at least 500, preferably 700, m 2/g. Independent claims are also included for the following: (1) a method for impregnating (A) with first an aqueous solution of a metal complex (I) and then with a solution of base (II); and (2) catalyst (B) for oxidation of mercaptans to disulfides that comprises (I) fixed to (A).
机译:活性炭(A)的总孔体积至少为1,优选为1.2ml / g。床层阻力(在壳层破碎试验中)至少为1,优选为1.7MPa,BET表面为至少500,优选为700m 2 / g。还包括以下方面的独立权利要求:(1)首先用金属络合物(I)的水溶液然后用碱(II)的溶液浸渍(A)的方法; (2)催化剂(B),用于将硫醇氧化成二硫化物,该催化剂(B)包含固定在(A)上的(I)。

著录项

  • 公开/公告号FR2865468A1

    专利类型

  • 公开/公告日2005-07-29

    原文格式PDF

  • 申请/专利权人 CECA SA;

    申请/专利号FR20040000568

  • 发明设计人 LE BEC REMI;

    申请日2004-01-22

  • 分类号C01B31/08;B01J20/20;B01J31/12;B01J31/18;B01J37/02;

  • 国家 FR

  • 入库时间 2022-08-21 21:58:15

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