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Preparation of a composition (2-, 3-, 4-, 5- or 6-phenylalkanes) comprises alkylation of aromatic composition by charge enclosing olefin in the presence of catalyst comprising a support and matrix at the base
Preparation of a composition (2-, 3-, 4-, 5- or 6-phenylalkanes) comprises alkylation of aromatic composition by charge enclosing olefin in the presence of catalyst comprising a support and matrix at the base
Preparation of a composition (2-, 3-, 4-, 5- or 6-phenylalkanes) comprises alkylation of aromatic composition by a charge enclosing an olefin (having at least 9 carbon atoms) in the presence of a catalyst comprising a support (a zeolite or mixture of zeolite) and a matrix (aluminum-silica) comprising silicon dioxide (greater than 5% and lesser than 95%) at the base. Preparation of a composition (2-, 3-, 4-, 5- or 6-phenylalkanes) comprises alkylation of aromatic composition by a charge enclosing an olefin (having at least 9 carbon atoms) in the presence of a catalyst comprising a support (a zeolite or mixture of zeolite) and a matrix (aluminum-silica) comprising silicon dioxide (greater than 5% and lesser than 95%) at the base, where the catalyst has: a mean porous diameter (20-140Å)-; total porous volume (0.1-0.6 ml/g)-; a porous volume (greater than 140 (preferably 500)Å and lesser than 0.1ml/g) in the pores measured by porosimeter with the mercury; specific surface BET (100-850 m2/g); density (0.65 g/cm3) of filling cup after calcination; total porous volume (0.1-0.6 ml/g) measured by nitrogen porosimeter; and an X-ray diffraction diagram containing the principle lines comprising at least a transition state aluminum (aluminum alpha , rho , khi, eta , gamma , kappa, theta or delta ), where the process occurs at 30-400[deg]C, 0.1-10 Mpa pressure, 0.5-200 h-1 spatial speed schedule and 1:1-50:1 molar ratio of aromatic/olefin composition.
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机译:组合物(2-,3-,4-,5-或6-苯基烷烃)的制备包括在包含载体的催化剂存在下,通过将烯烃(具有至少9个碳原子)包围起来的电荷将芳族组合物烷基化沸石或沸石的混合物)和基质(铝二氧化硅),在基质中包含二氧化硅(大于5%且小于95%)。组合物(2-,3-,4-,5-或6-苯基烷烃)的制备包括在包含载体的催化剂存在下,通过将烯烃(具有至少9个碳原子)包围起来的电荷将芳族组合物烷基化沸石或沸石的混合物)和在基质中包含二氧化硅(大于5%且小于95%)的基质(铝二氧化硅),其中催化剂的平均孔径为(20-140Å)-;总孔体积(0.1-0.6 ml / g)-;用孔隙率计用汞测量的孔中的孔隙体积(大于140(最好为500)Å,小于0.1ml / g);比表面积BET(100-850 m2> / g);煅烧后填充杯的密度(0.65 g / cm3>);用氮气孔隙率计测量的总孔体积(0.1-0.6 ml / g);和X射线衍射图,其包含至少包含过渡态铝(铝α,rho,khi,η,γ,κ,θ或δ)的主线,其中该过程在30-400℃下进行, 0.1-10 Mpa的压力,0.5-200 h-1的空间速度规程和1:1-50:1的芳香族/烯烃组合物摩尔比。
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