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The catalyst for oligomer conversion which designates eight nuclear nickel cluster as the base

机译:以八个核镍簇为基的低聚物转化催化剂

摘要

Conversion 1 According to this invention, from two seats which respectively include 4 nickel atoms making,(A) the 1st component general formula (i), and (b) being the Ni8 cluster which is the reaction product of the 2nd component which designates the complex general formula (ii) as the base, as for benzene ring it was possible here regarding the said 1st component, R and R'ha equality or differed, had the substituent to possess the substituent, 3 rank and/or 4 rank and/or 5 rank and/or in 6 rank or it had phenyl or the substituent which it does not have or it had shikuroarukiru or the substituent which it does not have or the carbon count to be able be chosen from alkyl 1 which it does not have - 20, as for Q the cationSo it is, it is chosen R from halogen or acetate in addition regarding the 2nd component, as for 2 arrows the catalyst component which features that the Ni8 cluster which has shown the fact that the region of 2 vacancies exists is designated as the base is offered. In addition according to this invention, catalyst system and method in order to do the oligomer conversion of olefin are offered.
机译:<转化1>根据本发明,从(A)第一成分通式(i),(b)为分别为包含4个镍原子的两个位置,作为第二成分的反应产物的Ni 8团簇。关于苯环,在此,可以将复杂的通式(ii)指定为碱基,关于上述第一成分,R和R'ha可以相同或不同,具有取代基具有3级和/或4级的取代基。和/或5位和/或6位,或具有苯基或不具有的取代基,或具有shikuroarukiru或不具有的取代基,或碳原子数可选自其所取代的烷基1 Q阳离子为-20,因此,就第二组分而言,还选自卤素或乙酸盐,R 2箭头所示的催化剂组分为具有Ni8簇特征的催化剂组分,其中指定存在2个职位空缺。另外,根据本发明,提供了用于进行烯烃的低聚物转化的催化剂体系和方法。

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