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The catalyst for oligomer conversion which designates eight nuclear nickel cluster as the base
The catalyst for oligomer conversion which designates eight nuclear nickel cluster as the base
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机译:以八个核镍簇为基的低聚物转化催化剂
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摘要
Conversion 1 According to this invention, from two seats which respectively include 4 nickel atoms making,(A) the 1st component general formula (i), and (b) being the Ni8 cluster which is the reaction product of the 2nd component which designates the complex general formula (ii) as the base, as for benzene ring it was possible here regarding the said 1st component, R and R'ha equality or differed, had the substituent to possess the substituent, 3 rank and/or 4 rank and/or 5 rank and/or in 6 rank or it had phenyl or the substituent which it does not have or it had shikuroarukiru or the substituent which it does not have or the carbon count to be able be chosen from alkyl 1 which it does not have - 20, as for Q the cationSo it is, it is chosen R from halogen or acetate in addition regarding the 2nd component, as for 2 arrows the catalyst component which features that the Ni8 cluster which has shown the fact that the region of 2 vacancies exists is designated as the base is offered. In addition according to this invention, catalyst system and method in order to do the oligomer conversion of olefin are offered.
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