shikurooruganiruhosuhuan and ji (alkaline metal/alkaline earths metal) synthetic method of origohosuhuanjiido

摘要

As for this invention, formula: R¹ PHal₂ (in formula, R¹, C₁ - C₁₂ alkyls, C₃ - C₁₂ shikuroarukiru, is aryl or hetero aryl, Hal, F, Cl and Br or is I, and as for n, it is number 3 - 20) with jiharo which is shown (oruganiru) hosuhuan, a) in the organic solvent activated zinc and, or b) by reacting with the alkaline metal or the alkaline earths metal in the non-polarized organic solvent, under existing of the activator, formula (i): (R¹ P) it regards the method of producing shikurooruganiruhosuhuan which is shown with _n. As for this invention, new ji (the alkaline metal/the alkaline earths metal) it regards also the use in producing origohosuhuanjiido, and the organic phosphorous compound.