The methane the catalyst and the method of transforming directly in acetic acid

摘要

This invention coordination was connected nitrogen and oxygen (N and O) the atom or oxygen and oxygen (O and O) by the atom, namely amino alcohol, (the hydroxy imino) di-carboxylic acid and hydroxy pillar non type, from torihuruoro acetic acid, it is torihuritsuku acid or inorganic acid the derivative, it possesses two seats or the multi seat ligands, the vanadium complex (oxidation state is +4 or +5), under mild condition and under existing of carbon monoxide or under non existing, and torihuruoro acetic acid (CF₃ COOH) the peroxo two sulfuration salt in (K₂ S₂ O₈)Under existing, directly the case of one pot transformation to the acetic acid of the methane, you use as a catalyst, on the basis of general formula (i).