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Three electrodes system cell for evaluation of performance of molten carbonate fuel cell

机译:三电极系统电池,用于评估熔融碳酸盐燃料电池的性能

摘要

Disclosed is a three electrodes system cell for evaluation of performance of a molten carbonate fuel cell. A lower part of the reference electrode is fixed to a wet seal part of the single cell without penetrating a current collector plate and an electrode of the single cell. Preferably, the reference electrode comprises cured matrix slurry and powders of electrolyte stacked on the matrix slurry in the lower part thereof. Preferably, a diameter of an electrolyte-interchanging hole formed in a bottom of the lower part of the reference electrode is 1ψ. Preferably, an outer diameter of an alumina tube in the reference electrode is 6ψ. According to a three electrodes system cell for evaluation of performance of a molten carbonate fuel cell of the invention, it is possible to separately evaluate the performance of each electrode which cannot be evaluated by the prior method of evaluating the performance of the single cell. Particularly, contrary to the prior art, it is possible to prevent a crack of the matrix due to a physical shock and a heat shock resulting from the outflow and inflow of the supply gas, to reduce the gas leakage resulting from a decrease of adhesive strength between the matrix and the alumina tube and a heat shock due to the gas leakage, to improve the problem of electrolyte depletion and to reduce the physical defects resulting from a size of the reference electrode. Accordingly, it is possible to clearly measure the variation of the performance of each electrode while reducing the physical errors to the highest degree, to provide an exact criterion regarding the factor influencing on the variation of performance of the single cell when evaluating the performance of the single cell having 100 cm2 of large area, and to directly evaluate the performance of the molten carbonate fuel cell.
机译:公开了一种用于评估熔融碳酸盐燃料电池的性能的三电极系统电池。参比电极的下部固定到单电池的湿密封部分,而不穿透集电板和单电池的电极。优选地,参比电极包括固化的基质浆料和堆叠在其下部中的基质浆料上的电解质粉末。优选地,形成在参比电极下部的底部中的电解质交换孔的直径为1ψ。优选地,参比电极中的氧化铝管的外径为6ψ。根据本发明的用于评估熔融碳酸盐燃料电池的性能的三电极系统电池,可以单独地评估每个电极的性能,而现有的评估单电池性能的方法不能评估每个电极的性能。特别地,与现有技术相反,可以防止由于供给气体的流出和流入所引起的物理冲击和热冲击而导致的基体破裂,从而减少由于粘合强度降低而引起的气体泄漏。在基体和氧化铝管之间的热膨胀和由于气体泄漏引起的热冲击,改善了电解质的耗竭问题,并减少了由参比电极尺寸引起的物理缺陷。因此,可以在最大程度地减小物理误差的同时清楚地测量每个电极的性能变化,以在评估电池的性能时提供关于影响单电池性能变化的因素的精确标准。具有100 cm 2 大面积的单电池,并直接评估熔融碳酸盐燃料电池的性能。

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