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OPTICAL TRANSPARENT SENSOR FOR DETECTING SULPHUR DIOXIDE (SO2) IN A GASEOUS SAMPLE

机译:气相样品中用于检测二氧化硫(SO2)的光学透明传感器

摘要

An optical transparent sensor is proposed for quantifying sulphur dioxide (SO2) in a gaseous sample. The sensor contains an indicator substance which is homogeneously immobilised in the sensor matrix, is brought into contact, at least indirectly, with the sample and the concentration of which changes in the presence of SO2. The change in concentration of the indicator substance can be advantageously followed photometrically as a change in light transmission through the sensor in the UV/VIS regions. The indicator substance is characterised in that it is present as a salt and derived from alkyl-substituted, alkylene-substituted or arylene-substituted ammonium ions of medium chain length, or from polymer anion exchange materials, while the counter-ion is formed from one or more chromium-oxygen compounds selected from the group comprising chromate CrO42- and/or dichromate Cr2O72- and/or polychromates.
机译:提出了一种光学透明传感器,用于量化气态样品中的二氧化硫(SO2)。该传感器包含均匀地固定在传感器基质中的指示剂物质,该指示剂物质至少间接地与样品接触,并且其浓度在存在SO2的情况下发生变化。指示剂物质的浓度的变化可以有利地以光度法跟随为在UV / VIS区域中通过传感器的光透射的变化。指示剂物质的特征在于它以盐形式存在,衍生自中等链长的烷基取代的,亚烷基取代的或亚芳基取代的铵离子,或衍生自聚合物阴离子交换材料,而抗衡离子则由一种选自铬酸盐CrO42-和/或重铬酸盐Cr2O72-和/或多铬酸盐的一种或多种铬-氧化合物。

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