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Electrolyte for rechargeable lithium battery including aluminum-based compounds as new anion receptors and rechargeable lithium battery
Electrolyte for rechargeable lithium battery including aluminum-based compounds as new anion receptors and rechargeable lithium battery
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机译:用于可充电锂电池的电解质,包括作为新阴离子受体的铝基化合物和可充电锂电池
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摘要
The present invention relates to a lithium secondary battery electrolyte and a lithium secondary battery containing an aluminum-based compound, and more particularly, to suppress the decomposition of anions by adding an aluminum compound as an anion-immobilizing material to a conventional lithium secondary battery electrolyte. The present invention relates to a lithium secondary battery including an electrolyte for lithium secondary batteries and a copper electrolyte capable of improving electrochemical stability, and increasing a cation yield of lithium ions to improve battery performance.;An object of the present invention is to provide a lithium secondary battery electrolyte containing an aluminum-based compound as an anion immobilization material of a lithium secondary battery electrolyte, and a lithium secondary battery containing the electrolyte.;The electrolyte solution for lithium secondary batteries of this invention shows the electrolyte solution for lithium secondary batteries containing the aluminum type compound represented by following formula (1) in the electrolyte solution for lithium secondary batteries containing a lithium salt and a water-insoluble organic solvent.; ..... Equation (1);In formula (1), R is CH 3 O, CF 3 CH 2 O, C 3 F 7 CH 2 O, (CF 3 ) 2 CHO, (CF 3 ) 2 C (C 6 H 5 ) O, (CF 3 ) 3 CO, C 6 H 5 O, FC 6 H 4 O, F 2 C 6 H 3 O, F 4 C 6 HO, C 6 F 5 O, CF 3 C 6 H 4 O, (CF 3 ) 2 C 6 H 3 O or C 6 F 5 .
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机译:锂二次电池电解质和包含铝基化合物的锂二次电池技术领域本发明涉及锂二次电池电解质和包含铝基化合物的锂二次电池,更具体地,通过将铝化合物作为阴离子固定材料添加到常规的锂二次电池电解质中来抑制阴离子的分解。 。锂二次电池技术领域本发明涉及一种锂二次电池,其包括能够改善电化学稳定性并提高锂离子的阳离子收率以改善电池性能的铜二次电池用电解质。包含铝基化合物作为锂二次电池电解质的阴离子固定材料的锂二次电池电解质,和含有该电解质的锂二次电池。本发明的锂二次电池用电解质溶液表示锂二次电池用电解质溶液。在含有锂盐和水不溶性有机溶剂的锂二次电池用电解液中含有下述式(1)表示的铝系化合物。 .....等式(1);在等式(1)中,R是CH 3 Sub> O,CF 3 Sub> CH 2 Sub> O,C 3 Sub> F 7 Sub> CH 2 Sub> O,(CF 3 Sub>) 2 Sub> CHO,( CF 3 Sub>) 2 Sub> C(C 6 Sub> H 5 Sub>)O,(CF 3 Sub >) 3 Sub> CO,C 6 Sub> H 5 Sub> O,FC 6 Sub> H 4 Sub> O,F 2 Sub> C 6 Sub> H 3 Sub> O,F 4 Sub> C 6 Sub> HO ,C 6 Sub> F 5 Sub> O,CF 3 Sub> C 6 Sub> H 4 Sub> O, (CF 3 Sub>) 2 Sub> C 6 Sub> H 3 Sub> O或C 6 Sub> F < Sub> 5 Sub>。
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