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production of di - t - alkyl peroxides and t - alkyl - hydroperoxiden starting from n - alkkyl - t - alkyl - aethern
production of di - t - alkyl peroxides and t - alkyl - hydroperoxiden starting from n - alkkyl - t - alkyl - aethern
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机译:从正烷基-叔烷基-醚醚开始制备二叔烷基过氧化物和叔烷基过氧化氢。
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摘要
A process for production of a t-alkyl peroxide compound includes the steps of:a) reacting an n-alkyl t-alkyl ether with a reactant mixture comprising an acid catalyst and a compound of the formula where R is H or t-alkyl, provided that if R is t-alkyl the t-alkyl peroxide compound product is a di-t-alkyl peroxide,andb) isolating a reaction product comprising said t-alkyl peroxide compound from the mixture resulting from step a).The process can be used to prepare t-butyl hydroperoxide or di-t-butyl peroxide from methyl t-butyl ether. Sulfuric acid may be used as the acid catalyst.
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