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ZEOLITE CATALYST FOR ALKYLATING ISOPARAFFIN-OLEFIN AND ALKYLATION METHOD OF ZEOLITE CATALYST

机译:烷基化异链烷烃-烯烃的沸石催化剂及该催化剂的烷基化方法

摘要

PROBLEM TO BE SOLVED: To provide a zeolite catalyst which controls the production of a hydrocarbon with a high boiling point or a carbonaceous material and is excellent in selectivity of gasoline fraction hydrocarbons; and also to provide an alkylation method using the zeolite catalyst.;SOLUTION: The zeolite catalyst for alkylating an isoparaffin-olefin consists of a beta zeolite wherein the beta zeolite contains lanthanum, and the proportion of lanthanum in the zeolite is 0.001-0.2 in terms of the ratio of lanthanum atom to silicon atom [La]/[Si], wherein the beta zeolite is synthesized by dry gel method and the average particle size is 0.01-1 μm. The isoparaffin-olefin alkylation method comprises bringing a mixture of isoparaffin and olefin of which the molar ratio (Mip/Mo) of the isoparaffin (Mip) and the olefin (Mo) is 2-50 into contact with the zeolite catalyst at a temperature of 25-150°C.;COPYRIGHT: (C)2007,JPO&INPIT
机译:解决的问题:提供一种沸石催化剂,其控制高沸点烃或碳质材料的产生,并且对汽油馏分烃的选择性优异。解决方案:用于使异链烷烃烯烃烷基化的沸石催化剂由β沸石组成,其中β沸石含有镧,并且镧在沸石中的比例为0.001-0.2。通过使用干凝胶法合成β沸石,并且平均粒径为0.01-1μm,镧原子与硅原子之比为[La] / [Si]。所述异链烷烃-烯烃烷基化方法包括使异链烷烃和烯烃的混合物在温度为200℃的条件下与异链烷烃(Mip)和烯烃(Mo)的摩尔比(Mip / Mo)为2-50的烯烃接触。 25-150&°C;版权:(C)2007,JPO&INPIT

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