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Precious metal colloid, precious metal fine-particle, composition, and method for producing precious metal fine-particle

机译:贵金属胶体,贵金属细粒,组合物和生产贵金属细粒的方法

摘要

To provide a precious metal colloid enabling a production in simply and in low cost, a long-term storage, and a formation of a thin film having a high conductivity, a precious metal fine-particle, a composition including the same, and a method for producing a precious metal fine-particle for forming such precious metal colloid, which is a precious metal colloid in which a protection component protects a precious metal fine-particle selected from gold, silver, platinum, and palladium, a precious metal colloid in which the maximum peak of 13C-NMR spectrum of the protection component separated from the precious metal colloid by ultracentrifugation treatment presents in 160 to 190 ppm other than peaks of a primary carbon and an aromatic carbon, or a precious metal colloid in which peaks of 13C-NMR spectrum present in 20 to 90 ppm and 160 to 190 ppm. A reduction agent, such as a peptide or other amino acid compound and glucosamine, and alkali for supporting a reductivity of the reduction agent are added to a solution dissolving a precious metal containing compound to form the precious metal fine-particle by a reduction reaction of a precious metal ion in the precious metal containing compound.
机译:提供一种贵金属胶体,贵金属微粒,包括该贵金属胶体的组合物和方法,该贵金属胶体能够以简单且低成本的方式生产,长期保存并形成具有高导电性的薄膜。用于制备用于形成这种贵金属胶体的贵金属微粒的方法,贵金属胶体是其中保护成分保护选自金,银,铂和钯的贵金属微粒的贵金属胶体,其中通过超速离心处理从贵金属胶体分离出的保护成分的 13 C-NMR谱图的最大峰除了伯碳或芳族碳或贵金属的峰以外,还存在160〜190ppm。金属胶体,其中 13 C-NMR谱图的峰存在于20至90 ppm和160至190 ppm。将诸如肽或其他氨基酸化合物和葡糖胺的还原剂和用于支持还原剂还原性的碱添加到溶解含贵金属的化合物的溶液中,以通过以下反应形成贵金属细粒:含贵金属的化合物中的贵金属离子。

著录项

  • 公开/公告号US2007186725A1

    专利类型

  • 公开/公告日2007-08-16

    原文格式PDF

  • 申请/专利权人 MASATOSHI WATABE;

    申请/专利号US20040569509

  • 发明设计人 MASATOSHI WATABE;

    申请日2004-06-21

  • 分类号C99Z99/00;

  • 国家 US

  • 入库时间 2022-08-21 21:07:13

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