首页> 外国专利> Polybenzazole compound having sulfonic acid group and/or phosphonic acid group, resin composition containing the same, resin molding, solid polymer electrolyte membrane, solid polymer electrolyte membrane/electrode assembly and method of preparing assembly

Polybenzazole compound having sulfonic acid group and/or phosphonic acid group, resin composition containing the same, resin molding, solid polymer electrolyte membrane, solid polymer electrolyte membrane/electrode assembly and method of preparing assembly

机译:具有磺酸基和/或膦酸基的聚苯并唑化合物,包含其的树脂组合物,树脂成型品,固体高分子电解质膜,固体高分子电解质膜/电极接合体及其制造方法

摘要

An object of the present invention is to obtain a novel polymeric material capable of forming a solid polymer electrolyte excellent not only in processability, solvent resistance and durability/stability but also in ion conductivity by introducing sulfonic acid group or phosphonic acid group into a polybenzazole compound having excellent properties in view of heat resistance, solvent resistance, mechanical characteristics and the like.;Means attaining the object of the present invention is a polybenzazole compound including an aromatic dicarboxylic acid bond unit having sulfonic acid group and/or phosphonic acid group and satisfying either a condition that inherent viscosity measured in concentrated sulfuric acid is in the range of 0.25 to 10 dl/g or a condition that inherent viscosity measured in a methanesulfonic acid solution is in the range of 0.1 to 50 dl/g.;The object of the present invention can be attained also by a resin composition containing the aforementioned polybenzazole compound, a resin molding, a solid polymer electrolyte membrane, a solid polymer electrolyte membrane/electrode assembly and a method of preparing the solid polymer electrolyte membrane/electrode assembly.
机译:本发明的目的是获得一种新型的高分子材料,该高分子材料能够通过将磺酸基或膦酸基引入聚苯并唑化合物中而形成不仅在加工性,耐溶剂性和耐久性/稳定性方面而且在离子传导性方面均优异的固体聚合物电解质。就耐热性,耐溶剂性,机械特性等而言,具有优异的特性。本发明的目的是提供一种包括具有磺酸基和/或膦酸基的芳香族二羧酸键单元且满足以下条件的聚苯并唑化合物。在浓硫酸中测得的特性粘度在0.25至10 dl / g范围内的条件下,或在甲磺酸溶液中测得的特性粘度在0.1至50 dl / g范围内的条件下;通过包含上述聚苯并唑的树脂组合物也可以实现本发明。化合物,树脂模制品,固体聚合物电解质膜,固体聚合物电解质膜/电极组件和制备固体聚合物电解质膜/电极组件的方法。

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