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Catalytic cleavage of phosphate ester bonds by boron chelates
Catalytic cleavage of phosphate ester bonds by boron chelates
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机译:硼螯合物对磷酸酯键的催化裂解
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摘要
Novel chemical compounds are disclosed having the general formula L{YXm}n, wherein X is selected from the Group 13 elements, Y is a halide, and L is a chelating ligand containing at least one binding atom contacting the Group 13 element, the atom being selected from the group consisting of C, N, O, and S, and m and n are integers having a value of at least 1. L may be a Schiff base type ligand, such as a salen ligand. The compositions of the present invention may be bidentate, quadridentate, or greater. The compositions may be used in dealkylation of phosphate esters or ethers. Advantageously, the methods of the present invention may be rendered catalytic.
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机译:公开了具有通式L {YX m Sub>} n Sub>的新型化合物,其中X选自13族元素,Y为卤化物,L为螯合剂含有至少一个与第13族元素接触的结合原子的配体,该原子选自C,N,O和S,并且m和n为值至少为1的整数。L可以为席夫碱基型配体,例如salen配体。本发明的组合物可以是二齿的,四齿的或更大的。该组合物可用于磷酸酯或醚的脱烷基。有利地,可以使本发明的方法具有催化性。
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