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AN IMPROVED PROCESS FOR PREPARATION OF CRYSTALLINE SAPO -11 TYPE NON-ZEOLITIC MOLECULAR SIEVE

机译:结晶SAPO -11型非沸石分子筛的制备工艺改进

摘要

: This invention relates to an improved process for preparation of crystalline SAPO-II type Non-Zeolitic Molecular Sieve comprising in the step of subjecting a reaction mixture wherein reaction mixture is prepared by adding phosphoric acid to an organic templating agent .containing carbon & nitrogen and aluminium isopr9poxide having an H20/ AI203 molar ratio of greater than 20, a reactive silicon dioxide having an average particle size of 10 to 30 nanometers, a sodium content of less than 0.03 wt% and bulk density of less than 0.1 g/ cc, said reaction mixture having a composition expressed in terms of mole ratios of (0.5-1.5) R : AI203: (0.1-1.0) SiO2 : (0.9-1.2) P20S : 20-100 H2O to:"! under crystallisation condition until crystals of non-zeolitic sieve are formed.
机译::本发明涉及一种制备结晶SAPO-Ⅱ型非沸石分子筛的改进方法,该方法包括以下步骤:使反应混合物经过处理,其中反应混合物是通过向有机模板剂中添加磷酸来制备的。H20 / Al2O3摩尔比大于20的氮气和异丙醇铝,平均粒径为10的活性二氧化硅30纳米至30纳米,钠含量小于0.03重量%,堆积密度小于0.1g / cc,所述反应混合物的组成表示为在结晶条件下直至非沸石晶体的摩尔比为(0.5-1.5)R:Al2O3:(0.1-1.0)SiO2:(0.9-1.2)P20S:20-100 H2O与:!!的摩尔比筛子形成。

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