首页> 外国专利> PROCESS FOR THE CONVERSION OF HEAVY CHARGES SUCH AS HEAVY CRUDE OILS AND DISTILLATION RESIDUES.

PROCESS FOR THE CONVERSION OF HEAVY CHARGES SUCH AS HEAVY CRUDE OILS AND DISTILLATION RESIDUES.

机译:重油转换过程,例如重质原油和蒸馏残渣。

摘要

Process for the conversion of heavy charges chosen among heavy and extra heavy crude oils, distillation residues, "heavy oils" coming from catalytic treatments, "thermal tars", bitu imen from oil sands, coals of various nature and other high boiling charges of hydrocarbon origin known as "black oils", by means of the joint use of at least three of the following process units: deasphalting (SDA1), hydroconversion with catalysts in slurry phase (HT1), distillation or flash (D), characterized by the fact of comprising the following stages: - sending the heavy charge to a deasphalting section (SDA1) in presence of a solvent obtaining two streams: one consisting of Deasphalted Oil (DAO1 from SDA1), the other one containing asphaltenes;- mixing the flow consisting of deasphalted oil (DAO1 from SDA1) with an appropriate hydrogenation catalyst and sending the thus obtained mixture to a hydroprocessing section (HT1) and introducing into it hydrogen or a mixture containing hydrogen and H2S; - m ixing the flow consisting of asphaltenes coming out of the deasphalting section (SDA1) with an appropriate hydrogenation catalyst and sending the thus obtained mixture to a second hydroprocessing section (HT2) and introducing into it hydrogen or a mixture containing hydrogen and H2S; - sending both the streams containing the reaction product of the hydroprocessing section (HT1) and the catalyst in the dispersed phase to one or more distillation or flash stages (D9)where the most volatile fractions, including the gases produced in the two hydroprocessing reactions (HT1 and HT2), are separated from the distillation residue (tar) or from the liquid coming out of the flash unit; -sending the distillation residue(tar) or the liquid coming out of the flash unit, containing the catalyst in the dispersed phase rich with metal sulfides, produced because of the demetallization of the charge, and possibly containing coke, to a second deasphalting section (SDA2) in presence of solvents , thus obt aining two streams, one consisting of deasphalted oil (DAO2 from SDA2) and the other consisting of asphaltenes, a part of which, unless some draining takes place, is recycled to the hydroprocessing section (HT1) and the other part is recycled to the second hydro iprocessing section (HT2).
机译:重质和超重质原油,蒸馏残渣,催化处理产生的“重油”,“热焦油”,油砂中的沥青,各种性质的煤炭以及其他高沸点烃装料中选择的重质装料的转化方法通过联合使用以下至少三个工艺单元来生产被称为“黑油”的产品:脱沥青(SDA1),淤浆相催化剂加氢转化(HT1),蒸馏或闪蒸(D),其特征在于所述方法包括以下步骤:-在溶剂的存在下将重装料送至脱沥青段(SDA1),获得两种物流:一种由脱沥青油(来自SDA1的DAO1)组成,另一种包含沥青质;-混合由以下组成的物流用适当的氢化催化剂脱沥青油(SDA1的DAO1),将得到的混合物送至加氢处理段(HT1),并向其中引入氢或含氢与H2S的混合物。 -将由脱沥青段(SDA1)出来的由沥青质组成的流与合适的氢化催化剂混合,并将由此获得的混合物送入第二加氢处理段(HT2),并向其中引入氢或含氢和H 2 S的混合物。 -将含有加氢处理段(HT1)的反应产物和分散相催化剂的物流都送至一个或多个蒸馏或闪蒸段(D9),其中最易挥发的馏分包括两次加氢处理反应中产生的气体( HT1和HT2)与蒸馏残余物(tar)或从闪蒸装置流出的液体分离; -将由闪蒸装置出来的蒸馏残留物(tar)或液体(由于进料的脱金属而产生的可能含有焦炭的分散相中含有富含金属硫化物的催化剂)送至第二个脱沥青段( SDA2)在溶剂的存在下,因此分成两股物流,一股由脱沥青油(来自SDA2的DAO2)组成,另一股由沥青质组成,除非发生某些排水,否则其中一部分将再循环至加氢处理段(HT1)另一部分则循环到第二加氢处理段(HT2)。

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