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Reagent and procedure for the synthesis of organic derivatives oxisulfurados and fluorinated.

机译:合成有机衍生物氧异硫脲和氟化的试剂和程序。

摘要

The invention relates to a reagent useful for the synthesis of organic derivatives OXISULFURADOS and fluorinated by reaction with a sulfur oxide, PARTICULARLY sulfur dioxide, characterized in that it comprises: A) an acid fluorocarboxylic OF FORMULA EA-CF {SUB 2} -COOH WHERE EA represents an atom or group that draws electrons, at least partially salified by a cation organic or MINERAL, b) an aprotic polar solvent, AND THE FACT THAT THE CONTENT CARRIED IN PROTON releasable for its various components, including impurities, is what SAME joined the MOLAR CONCENTRATION HALF OF INITIAL fluorocarboxylic said acid. This reagent can be implemented by heating to form sulfinic or sulfonic acids FLUORINATED.
机译:本发明涉及一种用于合成有机衍生物OXISULFURADOS并通过与二氧化硫特别是二氧化硫反应而氟化的试剂,其特征在于它包括:A)式EA-CF {SUB 2} -COOH的酸性氟代羧酸。 EA表示吸引电子的原子或基团,至少部分地被阳离子有机或矿物阳离子成盐,b)非质子极性溶剂,事实是质子中所含的各种成分(包括杂质)可释放的是相同的初始氟代羧酸的摩尔浓度为半酸。该试剂可以通过加热形成氟化的亚磺酸或磺酸来实现。

著录项

  • 公开/公告号ES2273343T3

    专利类型

  • 公开/公告日2007-05-01

    原文格式PDF

  • 申请/专利权人 RHODIA CHIMIE;

    申请/专利号ES19960400624T

  • 申请日1996-03-22

  • 分类号C07B45/04;C07C313/04;C07C303/02;C07C303/14;C07C309/06;C07C309/39;C07C309/80;C07C313/02;

  • 国家 ES

  • 入库时间 2022-08-21 20:54:29

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