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METHOD OF REDUCING A FUNCTIONAL GROUP IN AN OXIDISED FORM

机译:减少函数形式的函数组的方法

摘要

A novel method of reducing a functional group in an oxidised form. The invention relates more particularly to the reduction of aldehyde, ketone, ester, lactone, nitrile or phosphine oxide groups. The reduction method according to the invention is characterised in that it comprises exposing the substrate including the functional group to be reduced to the presence of a siloxane-type compound of the following formula (I), combined with a Lewis acid-type catalyst. In said formula (I): - R1 and R2, which are the same or different, are an alkyl, cycloalkyle or aryl group, - X is a digit from 0 to 50.
机译:还原氧化形式的官能团的新方法。本发明更具体地涉及醛,酮,酯,内酯,腈或氧化膦基团的还原。根据本发明的还原方法的特征在于,其包括将要还原的官能团的基材暴露于下式(I)的硅氧烷型化合物的存在下,并与路易斯酸型催化剂组合。在所述式(I)中:-相同或不同的R 1和R 2为烷基,环烷基或芳基,-X为0至50的数字。

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