首页> 外国专利> A melt-spun fibers from with metallocenes catalyzed random propylene - alpha - olefin - copolymers

A melt-spun fibers from with metallocenes catalyzed random propylene - alpha - olefin - copolymers

机译:茂金属熔纺纤维催化的无规丙烯-α-烯烃-共聚物。

摘要

A fiber product drawn from an isotactic propylene copolymer of a C2, C4, C5, C6, C7 or C8 &agr;-olefin monomer produced in the presence of a metallocene catalyst characterized by a bridged chiral and stereorigid cyclopentadienyl or substituted cyclopentadienyl ligand structure of a transitional metal selected from group 4b, 5b, or 6b metals of the Periodic Table of Elements, the copolymer having a MFR less than 35, suitably about 30 or less. The copolymer is heated to a molten state and extruded to form a fiber preform. The preform is subjected to spinning at a spinning speed of at least 300 meters per minutes and subsequent drawing at a speed of up to about 1500 meters per minute to provide a draw ratio of at least 1.5 up to 5:1 to produce a continuous fiber having high tenacity of about 3.5 grams per denier and greater and good hand.
机译:由C 2 ,C 4 ,C 5 ,C 6 的等规丙烯共聚物制成的纤维产品,C 7 或C 8 &agr;-烯烃单体在茂金属催化剂存在下生产,其特征在于过渡金属的手性和立体刚性的环戊二烯基或取代的环戊二烯基配体结构桥接选自元素周期表的4b,5b或6b族金属的共聚物的MFR小于35,合适地为约30或更小。将该共聚物加热至熔融状态并挤出以形成纤维预成型坯。以至少300米/分钟的纺丝速度对预成型件进行纺丝,随后以至多约1500米/分钟的速度拉伸,以提供至少1.5至5:1的拉伸比以生产连续纤维。具有约3.5克/旦的高韧性和更好的手感。

著录项

  • 公开/公告号DE60214299T2

    专利类型

  • 公开/公告日2007-09-13

    原文格式PDF

  • 申请/专利权人

    申请/专利号DE2002614299T

  • 发明设计人

    申请日2002-07-16

  • 分类号D01F6/30;

  • 国家 DE

  • 入库时间 2022-08-21 20:27:59

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